Lei, Zhen-Yao’s team published research in Organic & Biomolecular Chemistry in 2022 | 531-88-4

Organic & Biomolecular Chemistrypublished new progress about Amides Role: RCT (Reactant), RACT (Reactant or Reagent) (alkenyl). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Reference of 531-88-4.

Lei, Zhen-Yao; Hu, Kui; He, Yuan-Xiang; Geng, Shu; Chen, Li-Na; Zou, Shuai; Pan, Li; Ding, Zhi-Jun; Huang, Feng published the artcile< Visible light-induced N-radical 5-exo/6-endo cyclization of alkenyl amides: facile access to isoindolinones/isoquinolinones>, Reference of 531-88-4, the main research area is isoindolinone isoquinolinone preparation; alkenyl amide visible light radical cyclization.

An efficient N-centered radical intramol. cyclization reaction of alkenyl amides induced by visible light was described. In this process, an alkenyl amide underwent 5-exo/6-endo cyclization to selectively yield two critical alkaloid structures, namely isoindolinones and isoquinolinones.

Organic & Biomolecular Chemistrypublished new progress about Amides Role: RCT (Reactant), RACT (Reactant or Reagent) (alkenyl). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Reference of 531-88-4.

Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Liu, Bin’s team published research in Chinese Chemical Letters in 2019-03-31 | 531-88-4

Chinese Chemical Letterspublished new progress about Bases Role: RGT (Reagent), RACT (Reactant or Reagent). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Recommanded Product: 5,6-Dimethoxyisobenzofuran-1(3H)-one.

Liu, Bin; Zhou, Xigeng published the artcile< Synthesis of 1,2-phenylenedimethanols by base-promoted reduction of isobenzofuran-1(3H)-ones with silane>, Recommanded Product: 5,6-Dimethoxyisobenzofuran-1(3H)-one, the main research area is phenylenedimethanol preparation isobenzofuranone reduction base silane.

An efficient method for preparation of substituted 1,2-phenylenedimethanols and aliphatic 1,4-diols that are valuable intermediates in organic synthesis, was developed by the base-promoted reduction of isobenzofuran-1(3H)-ones and γ-lactones with silane under mild conditions. Compared with traditional procedures using stoichiometric amounts of metal hydrides and alkyl reductants, the present method avoids the use of sensitive reagents and is operationally simple and a broad variety of functional groups are tolerated.

Chinese Chemical Letterspublished new progress about Bases Role: RGT (Reagent), RACT (Reactant or Reagent). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Recommanded Product: 5,6-Dimethoxyisobenzofuran-1(3H)-one.

Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Li, Junxuan’s team published research in Science China: Chemistry in 2022-01-31 | 531-88-4

Science China: Chemistrypublished new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Category: benzofurans.

Li, Junxuan; Zhou, Jinlei; Wang, Yumei; Yu, Yue; Liu, Qiang; Yang, Tilong; Chen, Huoji; Cao, Hua published the artcile< Mechanistic insight into the synergistic Cu/Pd-catalyzed carbonylation of aryl iodides using alcohols and dioxygen as the carbonyl source>, Category: benzofurans, the main research area is aryl iodide alc carbonylation dioxygen carbonyl source mechanistic insight.

Pd-catalyzed carbonylation, as an efficient synthetic approach for the installation of carbonyl groups in organic compounds, has been one of the most important research fields in the past decade. Although elegant reactions that allow highly selective carbonylations have been developed, straightforward routes with improved reaction activity and broader substrate scope remain long-term challenges for new practical applications. Here, authors show a new type of synergistic Cu/Pd-catalyzed carbonylation reaction using alcs. and dioxgen as the carbonyl sources. A broad range of aryl iodides and alcs. are compatible with this protocol. The reaction is concise and practical due to the ready availability of the starting materials and the scalability of the reaction. In addition, the reaction affords lactones and lactams in an intermol. fashion. Moreover, DFT calculations have been performed to study the detailed mechanisms.

Science China: Chemistrypublished new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Category: benzofurans.

Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Ibrahimi, Maroua’s team published research in Synlett in 2021-02-28 | 531-88-4

Synlettpublished new progress about Benzaldehydes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Recommanded Product: 5,6-Dimethoxyisobenzofuran-1(3H)-one.

Ibrahimi, Maroua; Khoumeri, Omar; Abderrahim, Raoudha; Terme, Thierry; Vanelle, Patrice published the artcile< Synthesis of 3-Benzylphthalide Derivatives by Using a TDAE Strategy>, Recommanded Product: 5,6-Dimethoxyisobenzofuran-1(3H)-one, the main research area is benzylphthalide preparation; nitrobenzyl chloride tetrakisdimethylaminoethylene formylbenzoate nucleophilic addition.

A one-pot synthesis of new 3-benzylphthalide derivatives I (X = CH, N; R1 = 4-NO2, 3-OMe-4-NO2, 2-NO2-4-C6H4, etc.; R2 = 4-CN, 5-Cl, 4-COOMe, etc.) was developed by using a strategy based on tetrakis(dimethylamino)ethylene (TDAE). The reactions in the presence of TDAE of substituted benzyl chlorides with Me 2-formylbenzoate or of substituted methyl-2-formylbenzoates with 4-nitrobenzyl chloride furnished the corresponding isobenzofuran-1(3H)-one products in moderate to good yields.

Synlettpublished new progress about Benzaldehydes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 531-88-4 belongs to class benzofurans, and the molecular formula is C10H10O4, Recommanded Product: 5,6-Dimethoxyisobenzofuran-1(3H)-one.

Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem