Category: 2923-28-6

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 2923-28-6, is researched, SMILESS is O=S(C(F)(F)F)([O-])=O.[Ag+], Molecular CAgF3O3SJournal, Article, Dalton Transactions called The effect of sodium thiosulfate on cytotoxicity of a diimine Re(I) tricarbonyl complex, Author is Capper, Miles S.; Enriquez Garcia, Alejandra; Lai, Barry; Wang, Baiwen O.; Gelfand, Benjamin S.; Shemanko, Carrie S.; Jalilehvand, Farideh, the main research direction is crystal structure rhenium bipyridine thiosulfate carbonyl; rhenium bipyridine thiosulfate carbonyl preparation breast cancer cytotoxicity.Application In Synthesis of Silver(I) trifluoromethanesulfonate.

Recently, diimine Re(I) tricarbonyl complexes have attracted great interest due to their promising cytotoxic effects. Here, the authors compare the cytotoxicity and cellular uptake of two Re(I) compounds fac-[Re(CO)3(bpy)(H2O)](CF3SO3) (1) and Na(fac-[Re(CO)3(bpy)(S2O3)])·H2O (bpy = 2,2′-bipyridine) (2). The Re-thiosulfate complex in 2 was characterized in two solvated crystal structures {Na(fac-[Re(CO)3(bpy)(S2O3)])·1.75H2O·EtOH}4 (2 + 0.75H2O + EtOH)4 and (fac-[Re(CO)3(bpy)(H2O)]) (fac-[Re(CO)3(bpy)(S2O3)])·4H2O (3). The cytotoxicity of 1 and 2 was tested in the MDA-MB-231 breast cancer cell line and compared with that of cisplatin. The cellular localization of the Re(I) complexes was studied using synchrotron-based x-ray fluorescence microscopy (XFM). Replacement of the aqua ligand with thiosulfate renders the complex less toxic most likely by disrupting its cellular entry. Therefore, thiosulfate could potentially have a similar chemoprotective effect against diimine fac-Re(CO)3 complexes as it has against cisplatin.

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Zhao, Yifan; Zhang, Jian; Guo, Juchen published an article about the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6,SMILESS:O=S(C(F)(F)F)([O-])=O.[Ag+] ).Related Products of 2923-28-6. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:2923-28-6) through the article.

The implementation of a low electrolyte/sulfur (E/S) ratio is essential to achieving high specific energy for lithium‖sulfur (Li‖S) batteries. In reality, however, the lean electrolyte condition results in low achievable capacity and inferior cyclability. In this study, we probe the interfacial processes on the sulfur cathode under the lean electrolyte condition using operando electrochem. impedance spectroscopy (EIS) and a galvanostatic intermittent titration technique (GITT). The operando EIS reveals a significant and rapid increase in the charge-transfer resistance during the transition from high-order polysulfides to low-order ones at a low E/S ratio, which is induced by a kinetic bottleneck at the interphase due to Li-ion mass transfer limitation. The GITT results confirm the kinetic bottleneck by revealing a large discharge overpotential during the transition phase. We further demonstrate that improving the adsorption of dissolved high-order polysulfides, a key step in the interfacial processes, can alleviate the kinetic limitation, thus enhancing the achievable capacity under the lean electrolyte condition.

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 2923-28-6, is researched, Molecular CAgF3O3S, about Design, synthesis, and validation of a novel [11C]promethazine PET probe for imaging Abeta using autoradiography, the main research direction is promethazine 11C preparation image Abeta autoradiog; Abeta; Alzheimer; PET imaging; autoradiography; promethazine.Recommanded Product: Silver(I) trifluoromethanesulfonate.

In this work, authors report the design and synthesis of a novel [11C]promethazine PET radioligand for future in vivo studies. The [11C]promethazine was isolated by RP-HPLC with radiochem. purity >95% and molar activity of 48 TBq/mmol. The specificity of the probe was demonstrated using human hippocampal tissues via autoradiog.

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Nazish, Mohd; Legendre, Christina M.; Sarkar, Samir Kumar; Luecken, Jana; Goffitzer, Daniel J.; Diefenbach, Martin; Schwederski, Brigitte; Herbst-Irmer, Regine; Stalke, Dietmar; Holthausen, Max C.; Kaim, Wolfgang; Roesky, Herbert W. published the article 《Selective Route to Stable Silicon-Boron Radicals and Their Corresponding Cations》. Keywords: stable silicon boron radical cation preparation crystal mol structure; mol structure calculation electrochem redox silicon boron radical cation.They researched the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6 ).Formula: CAgF3O3S. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:2923-28-6) here.

Herein, authors report on a facile and selective one-pot synthetic route to silicon-boron radicals. Reduction of Br2BTip (Tip = 2,4,6-iPrC6H2) with KC8 in the presence of LSi-R affords LSi(tBu)-B(Br)Tip (1) and LSi(N(TMS)2)-B(Br)Tip (2) [L = PhC(NtBu)2]. These first examples of silicon-boron isolated radical species feature spin d. on the silicon and boron atoms. 1 And 2 exhibit extraordinary stability to high temperatures under inert conditions in solution and air stability in the solid state. Both radicals have been isolated and fully characterized by ESR spectroscopy, SQUID magnetometry, mass spectrometry, cyclic voltammetry, single-crystal x-ray structure anal., and d. functional theory calculations Moreover, compound 1 exhibits one-electron transfer when treated with 1 equivalent of AgSO3CF3 and [Ph3C]+[B(C6F5)4]-, resp., resulting in the corresponding cations [LSi(tBu)-B(Br)Tip]+[CF3SO3]- (3) and [LSi(tBu)-B(Br)Tip]+[B(C6F5)4]- (4). Compounds 3 and 4 have been characterized with multinuclear NMR and mass spectrometry.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Catalytic hydrogenation enabled by ligand-based storage of hydrogen.Reference of Silver(I) trifluoromethanesulfonate.

Biol. employs exquisite control over proton, electron, H-atom, or H2 transfer. Similar control in synthetic systems has the potential to facilitate efficient and selective catalysis. Here we report a dihydrazonopyrrole Ni complex where an H2 equivalent can be stored on the ligand periphery without metal-based redox changes and can be leveraged for catalytic hydrogenations. Kinetic and computational anal. suggests ligand hydrogenation proceeds by H2 association followed by H-H scission. This complex is an unusual example where a synthetic system can mimic biol.′s ability to mediate H2 transfer via secondary coordination sphere-based processes.

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Benzofuran – Wikipedia,
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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Cu(II) and Ag(I) complexes of the pyrazole-derived diorganoselenide (pzCH2CH2)2Se. Synthesis, solid state structure and solution behavior.Electric Literature of CAgF3O3S.

The diorganoselenide (pzCH2CH2)2Se (R2Se (1), pz = pyrazole) was prepared by reacting the in situ obtained Na2Se with 1-(2-bromoethyl)-1H-pyrazole in a water/ethanol mixture Copper(II) and silver(I) complexes of type [CuX2{Se(CH2CH2pz)2}] [X = Cl (2), Br (3), NO3 (4), ClO4 (5)] and [AgX{Se(CH2CH2pz)2}] [X = OTf (6) (OTf = CF3SO3), NO3 (7), ClO4 (8)] were obtained by reacting the ligand 1 with the appropriate copper(II) and silver(I) salt in 1:1 molar ratio. The ligand and the metal complexes were investigated by appropriate spectroscopic methods, both in solution and in solid state: multinuclear NMR (1H, 13C, 19F, 77Se), UV-Vis spectroscopy, ESI mass spectrometry, IR spectroscopy and molar conductivity The metal complexes 2, 3 and 6-8 behave as 1:1 electrolytes in solution, while 4 and 5 behave as 1:2 electrolytes. The mol. structures of complexes [CuX2{Se(CH2CH2pz)2}] [X = Cl (2), Br (3), NO3 (4)], [Cu(ClO4)2{Se(CH2CH2pz)2}(H2O)] (5·H2O) and [AgOTf{Se(CH2CH2pz)2}] (6) were determined by single-crystal X-ray diffraction. The (pzCH2CH2)2Se ligand acts as a N,Se,N chelating moiety in 2, 3, 4 and 5·H2O and as a bridging, tetraconnective 2 x N,Se unit in 6.

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COA of Formula: CAgF3O3S. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about X-ray crystal structure of [L2Ag3]+[OTf].5C6D6: a monoanionic bisphosphinimine ligand supported trisilver complex. Author is Drescher, Sam L.; Forfar, Christopher P.; Boere, Rene T.; Hayes, Paul G..

The compound bis{μ3-2, 5-bis[N-(4-isopropylphenyl)-P, P-diphenylphosphorimidoyl]pyrrol-1-ido-Κ3N:N’:N’:’}trisilver(I) trifluoromethanesulfonate deuterated benzene pentasolvate, [Ag3(C46H44N3P2)2](CF3O3S)5C6D6, (I), was synthesized from two equivalent of NaL [L = 2,5-(4-iPrC6H4N=PPh2)C4H2N] and three equivalent of AgOTf (OTf = OSO2CF3). High-quality crystals of (I) formed with five deuterated benzene solvent mols. in the asym. unit. Notably, the bond lengths and angles between the three silver atoms are markedly different, unlike in most other reported trisilver complexes that tend to form three equivalent metal centers. Addnl., to the best of our knowledge, this is the first report of a trisilver complex with six nitrogen donors from two bisphosphinimine ligands.

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Benzofuran – Wikipedia,
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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 2923-28-6, is researched, Molecular CAgF3O3S, about Silver in the Center Enhances Room-Temperature Phosphorescence of a Platinum Sub-nanocluster by 18 Times, the main research direction is platinum silver octanethiolate subnanocluster aggregation induced ambient phosphorescence enhancement; metal clusters; nanoparticles; photoluminescence; platinum; silver.COA of Formula: CAgF3O3S.

There was controversy surrounding the roles of the metal core (metal-metal interaction) and the shell (metal-ligand interaction) in luminescence of ligand-protected metal nanoclusters. The authors aggregation-induced room-temperature phosphorescence of a Pt octanethiolate complex and its Ag ion inclusion complex (a Ag-doped Pt sub-nanocluster) was discovered. The inclusion of Ag ion boosted the photoluminescent quantum yield by 18 times. Photophys. measurements indicate that the rate of nonradiative decay was slower for the Ag-doped Pt sub-nanocluster. DFT calculations showed that the LUMO, which had the main contribution from Ag s-orbital and Pt d-orbitals, played a critical role in suppressing the structural distortion at the excited state. This work will hopefully stimulate more research on designing strategies based on MOs of atomicity-precise luminescent multimetallic nanoclusters.

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The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6 ) is researched.Quality Control of Silver(I) trifluoromethanesulfonate.Waters, Jessica E.; Berger, Georg; Peel, Andrew J.; Garcia-Rodriguez, Raul; Bond, Andrew D.; Wright, Dominic S. published the article 《Uncovering the Hidden Landscape of Tris(4-pyridyl) Ligands: Topological Complexity Derived from the Bridgehead》 about this compound( cas:2923-28-6 ) in Chemistry – A European Journal. Keywords: preparation tin antimony bismuth trispyridyl ligand complex; crystal structure tin antimony bismuth trispyridyl ligand complex; structure directing tin antimony bismuth trispyridyl ligand complex; coordination networks; main-group synthesis; pnictogens; topology; tripodal ligands. Let’s learn more about this compound (cas:2923-28-6).

Supramol. main group chem. is a developing field which parallels the conventional domain of metallo-organic chem. Little explored building blocks in this area are main group metal-based ligands which have the appropriate donor symmetry to build desired mol. or extended arrangements. Tris(pyridyl) main group ligands (E(py)3, E = main group metal) are potentially highly versatile building blocks since shifting the N-donor arms from the 2- to the 3-positions and 4-positions provides a very simple way of changing the ligand character from mononuclear/chelating to multidentate/metal-bridging. Here, the coordination behavior of the first main group metal tris(4-pyridyl) ligands, E(4-py)3 (E = Sb, Bi, Ph-Sn) is explored, as well as their ability to build metal-organic frameworks (MOFs). The complicated topol. of these MOFs shows a marked influence on the counteranion and on the ability of the E(4-py)3 ligands to switch coordination mode, depending on the steric and donor character of the bridgehead. This structure-directing influence of the bridgehead provides a potential building strategy for future mol. and MOF design in this area.

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Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

COA of Formula: CAgF3O3S. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Anticancer and antibacterial potential of robust Ruthenium(II) arene complexes regulated by choice of α-diimine and halide ligands. Author is Zanda, Emanuele; Busto, Natalia; Biancalana, Lorenzo; Zacchini, Stefano; Biver, Tarita; Garcia, Begona; Marchetti, Fabio.

Several complexes of general formula [Ru(halide)(η6-p-cymene)(α-diimine)]+, in the form of nitrate, triflate and hexafluorophosphate salts, including a newly synthesized iodide compound, were investigated as potential anticancer drugs and bactericides. NMR and UV-Vis studies evidenced remarkable stability of the complexes in water and cell culture medium. In general, the complexes displayed strong cytotoxicity against A2780 and A549 cancer cell lines with IC50 values in the low micromolar range, and one complex (RUCYN) emerged as the most promising one, with a significant selectivity compared to the non-cancerous HEK293 cell line. A variable affinity of the complexes for BSA and DNA binding was ascertained by spectrophotometry/fluorimetry, CD, electrophoresis and viscometry. The performance of RUCYN appears associated to enhanced cell internalization, favored by two cyclohexyl substituents, rather than to specific interaction with the evaluated biomols. The chloride/iodide replacement, in one case, led to increased cellular uptake and cytotoxicity at the expense of selectivity, and tuned DNA binding towards intercalation. Complexes with iodide or a valproate bioactive fragment exhibited the best antimicrobial profiles.

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Benzofuran – Wikipedia,
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