Category: 2923-28-6

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called New 3D Porous Silver Nanopolycluster as a Highly Effective Supercapacitor Electrode: Synthesis and Study of the Optical and Electrochemical Properties, published in 2021-02-01, which mentions a compound: 2923-28-6, mainly applied to supercapacitor electrode porous silver nanopolycluster preparation crystal structure, Application In Synthesis of Silver(I) trifluoromethanesulfonate.

A high-nucleus silver nanopolycluster as a new type of silver-based polymer supercapacitor (SSc) by a simple and single-step synthesis process was designed and synthesized. The structural, optical, and electrochem. properties of SSc-2 were determined This highly stable conductive 3D nanopolycluster shows great cycling stability, large capacity, and high energy d. without any modification or doping process and so acts as an excellent SSc (412 F g-1 at 1.5 A g-1). In addition, there was a stable cycling performance (94% capacitance) following 7000 cycles at 3 A g-1 c.d. The presence of fluorinated groups, 3D expansion of high-nucleus metallic clusters, and porosity are the advantages of SSc-2 that lead to stability, conductivity, and high capacity, resp. These results lead to the development of a novel kind of SSc by overcoming the low conductivity and limited capacity challenges without any modification. A new porous silver nanopolycluster with a unique supercapacitor (SSc) property was synthesized, and its structural, optical, and electrochem. properties were determined This 3D nanopolycluster without any modification or doping process acts as an excellent SSc (412 F g-1 at 1.5 A g-1).

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Recommanded Product: 2923-28-6. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Stimuli-Responsive Topological Transformation of a Molecular Borromean Ring via Controlled Oxidation of Thioether Moieties. Author is Zhang, Hai-Ning; Yu, Wei-Bin; Lin, Yue-Jian; Jin, Guo-Xin.

A Cp*-Rh based D-shaped binuclear metallacycle and a template-free mol. Borromean ring (BR) were obtained in high yield using the semi-rigid thioether dipyridyl ligand 1,4-bis[(pyridin-4-ylthio)methyl]benzene (Bptmb). The topol. transformation from a binuclear metallacycle and a BR to tetranuclear metallacycles was realized via the controlled oxidation of thioethers. The strategy used in this work can be regarded as a new form of stimuli-responsive post-synthesis modification (PSM).

If you want to learn more about this compound(Silver(I) trifluoromethanesulfonate)Recommanded Product: 2923-28-6, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(2923-28-6).

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 2923-28-6, is researched, Molecular CAgF3O3S, about Structure of copper(I) and silver(I) complexes with zwitterionic ligands derived from N-Heterocyclic Carbenes, the main research direction is copper silver bisdiisopropylphenylimidazolylidene complex preparation; crystal structure copper silver bisdiisopropylphenylimidazolylidene complex.Electric Literature of CAgF3O3S.

N-Heterocyclic Carbene (NHC) ligands have been instrumental in the synthesis of novel metal and main group-containing compounds, as well as their subsequent reactivity. Here, the coordination chem. of CS2 and PhNCS derivatives of the sterically encumbering 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) are studied. The reaction of IPr•CS2 with Cu(I) and Ag(I) salts results in the isolation of dinuclear complexes, [(IPr•CS2)2M2(THF)n][X]2, M = Cu, X = PF6, n = 4; M = Ag, X = OTf, n = 2. The 1:1 stoichiometric reaction of IPr•PhNCS with CuI results in to the formation of [(IPr•PhNCS)2Cu][CuI2]. All complexes were characterized by 1H, 13C, and IR spectroscopy and their solid-state structures determined by X-ray crystallog.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Computed Properties of CAgF3O3S. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Computational Insights into Different Mechanisms for Ag-, Cu-, and Pd-Catalyzed Cyclopropanation of Alkenes and Sulfonyl Hydrazones. Author is Wu, Yong; Cao, Shanshan; Douair, Iskander; Maron, Laurent; Bi, Xihe.

The [2+1] cycloaddition reaction of a metal carbene with an alkene can produce important cyclopropane products for synthetic intermediates, materials, and pharmaceutical applications. However, this reaction is often accompanied by side reactions, such as coupling and self-coupling, so that the yield of the cyclopropanation product of non-silver transition-metal carbenes and hindered alkenes is generally lower than 50%. To solve this problem, the addition of a low concentration of diazo compound (decomposition of sulfonyl hydrazones) to alkenes catalyzed by either CuOAc or PdCl2 was studied, but side reactions could still not be avoided. Interestingly, however, the yield of cyclopropanation products for such hindered alkenes were as high as 99% with AgOTf as a catalyst. To explain this unexpected phenomenon, reaction pathways have been computed for four different catalysts by using DFT. By combining the results of these calculations with those obtained exptl., it can be concluded that the efficiency of the silver catalyst is due to the barrierless concerted cycloaddition step and the kinetic inhibition of side reactions by a high concentration of alkene.

There is still a lot of research devoted to this compound(SMILES：O=S(C(F)(F)F)([O-])=O.[Ag+])Computed Properties of CAgF3O3S, and with the development of science, more effects of this compound(2923-28-6) can be discovered.

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Product Details of 2923-28-6. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Gas sorption of nano-porous supramolecules formed by multi-hydrogen bonded coordination capsules.

[{ReI(CO)3(Hbim)}3(tpta)]2 (1, Hbim- = 2,2′-biimidazolate monoanion, tpta = 2,4,6-tripyridyl-1,3,5-triazine) was prepared as a nano-space supramol. by using a new group of H-bonded coordination capsules. The hamburger bun-shaped half unit [{ReI(CO)3(Hbim)}3(tpta)] contains six intermol. H-bonds of Hbim- ligands with complementary dual NH···N types, and three [ReI(CO)3(Hbim)] are coordinated by bridging tridentate tpta. Interestingly, mech. grinding easily would convert single crystals of 1 to an amorphous state with minor crystallinity while maintaining the nano-space pores. The ground sample can reversibly uptake and release small mols. such as CO2 and (CH2Cl)2.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Synthesis, structural characterization, and bonding analysis of two-coordinate copper(I) and silver(I) complexes of pyrrole-based bis(phosphinimine): new metal-pyrrole ring π-interactions, published in 2021, which mentions a compound: 2923-28-6, mainly applied to copper silver pyrrole phosphinimine complex preparation crystal mol structure; electron density aromaticity copper silver pyrrole phosphinimine complex, COA of Formula: CAgF3O3S.

The reaction between 2,5-bis(diphenylphosphinomethyl)pyrrole and Me3SiN3 gave the new pyrrole-based bis(phosphinimine) L1H in an excellent yield. L1H reacts with [CuCl(COD)]2, AgBF4, or AgOTf to give the corresponding two-coordinate mononuclear ionic complex formulated as [M{(L1H)-κ2N,N}]+[X]- where M = Cu and Ag; X = [CuCl2], BF4 or OTf. Their single crystal x-ray diffraction studies confirmed the two-coordinate geometry formed by the chelate bonding mode of L1H. These 10-membered metalacycles exhibit planar chirality and were also characterized by spectroscopic methods. In addition, in all three structures, there exists a hitherto unknown π-interaction between the pyrrole ring atoms and metal, represented as η2-(Cα-N) in the copper(I) complex, and η3-(Cα-N-Cα’) in the silver(I) complexes. These weak interactions were supported by DFT calculations in terms of their electron densities, non-covalent interaction plots and the decrease in the aromaticity of the pyrrole ring.

If you want to learn more about this compound(Silver(I) trifluoromethanesulfonate)COA of Formula: CAgF3O3S, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(2923-28-6).

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Electric Literature of CAgF3O3S. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Synthesis, crystal structure and photophysical properties of bis[2,6-difluoro-3-(pyridin-2-yl)pyridine-κN](trifluoromethanesulfonato-κO)silver(I). Author is Moon, Suk-Hee; Paek, Sanghyun; Kang, Youngjin.

In the title compound, [Ag(CF3SO3)(C10H6F2N2)2], the AgI center adopts a highly distorted trigonal-planar coordination environment resulting from its coordination by one O atom of the trifluoromethanesulfonate anion and the pyridine N atoms of two crystallog. independent 2′,6′-difluoro-2,3′-bipyridine ligands, which display very similar conformations to one another. Pairwise Ag···O-SO2CF3- [Ag···O = 2.8314 (14) Å] interactions and intermol. C-H···O interactions between inversion-related units lead to the formation of an eight-membered cyclic dimer in which the silver atoms are separated by 6.2152 (3) Å. In the crystal, the dimers are linked through C-H···O hydrogen bonds, halogen···π and weak π-π stacking interactions, resulting in the formation of a three-dimensional supramol. network. The title compound exhibits a strong and broad emission band from 400 nm to 550 nm in solution and its photoluminescence quantum efficiency is estimated to be ca 0.2, indicating that the title compound could have applications as an emitting material in organic light-emitting diodes (OLEDs).

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

He, Meixia; Lehn, Jean-Marie published an article about the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6,SMILESS:O=S(C(F)(F)F)([O-])=O.[Ag+] ).Recommanded Product: Silver(I) trifluoromethanesulfonate. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:2923-28-6) through the article.

Optimizing C=N bond formation and C/N component exchange has major significance in dynamic covalent chem. (DCC). Imine and hydrazone generation from their aldehyde, amine and hydrazine components showed large accelerations in presence of AgOTf or Zn(OTf)2, up to 104 for the Zn(II)-(p-anisidine)imine complex. Zn(OTf)2 and auxiliary p-anisidine together accelerated 630 times the formation of the Zn(II)-hydrazone complex, revealing a strong synergistic effect, traced to very fast initial formation of the reactive Zn(II)-imine complex presenting a C=N bond metallo-activated towards reaction with the hydrazine component. Reactions involving more entities showed kinetically faster and thermodynamically simpler outputs due to dynamic competition within a mixture of higher complexity. Catalytic amounts of metal salts and auxiliary amine gave similar marked rate accelerations and turnover, indicating true catalysis. The synergistic effect achieved by combining metallo- and organo-catalysis points to a powerful co-catalysis strategy of bond-formation in DCC through interconnected chem. transformations.

Here is a brief introduction to this compound(2923-28-6)Recommanded Product: Silver(I) trifluoromethanesulfonate, if you want to know about other compounds related to this compound(2923-28-6), you can read my other articles.

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem