Discovery of 2923-28-6

Here is a brief introduction to this compound(2923-28-6)Recommanded Product: Silver(I) trifluoromethanesulfonate, if you want to know about other compounds related to this compound(2923-28-6), you can read my other articles.

He, Meixia; Lehn, Jean-Marie published an article about the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6,SMILESS:O=S(C(F)(F)F)([O-])=O.[Ag+] ).Recommanded Product: Silver(I) trifluoromethanesulfonate. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:2923-28-6) through the article.

Optimizing C=N bond formation and C/N component exchange has major significance in dynamic covalent chem. (DCC). Imine and hydrazone generation from their aldehyde, amine and hydrazine components showed large accelerations in presence of AgOTf or Zn(OTf)2, up to 104 for the Zn(II)-(p-anisidine)imine complex. Zn(OTf)2 and auxiliary p-anisidine together accelerated 630 times the formation of the Zn(II)-hydrazone complex, revealing a strong synergistic effect, traced to very fast initial formation of the reactive Zn(II)-imine complex presenting a C=N bond metallo-activated towards reaction with the hydrazine component. Reactions involving more entities showed kinetically faster and thermodynamically simpler outputs due to dynamic competition within a mixture of higher complexity. Catalytic amounts of metal salts and auxiliary amine gave similar marked rate accelerations and turnover, indicating true catalysis. The synergistic effect achieved by combining metallo- and organo-catalysis points to a powerful co-catalysis strategy of bond-formation in DCC through interconnected chem. transformations.

Here is a brief introduction to this compound(2923-28-6)Recommanded Product: Silver(I) trifluoromethanesulfonate, if you want to know about other compounds related to this compound(2923-28-6), you can read my other articles.

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem