Category: 2923-28-6

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Silver(I) trifluoromethanesulfonate(SMILESS: O=S(C(F)(F)F)([O-])=O.[Ag+],cas:2923-28-6) is researched.HPLC of Formula: 70539-42-3. The article 《Synthesis, Structure, and Reactivity of Acid-Free Neutral Oxoborane》 in relation to this compound, is published in Angewandte Chemie, International Edition. Let’s take a look at the latest research on this compound (cas:2923-28-6).

Carborane- and NHC-stabilized oxoborane 2-(TfO)-o-C2B10H10-1-B(:O)-IDipp [IDipp = 1,3-bis(diisopropylphenyl)-2-imidazolylidene] was prepared by reaction of AgOTf with 1,2-BBr(IDipp)-o-C2B10H10; its structure was confirmed by single-crystal x-ray diffraction. An efficient synthesis of an acid-free neutral oxoborane of the type carboranyl-B(carbene):O has been developed via a serendipitous discovery from the reaction of 1,2-[BBr(carbene)]-o-carborane with AgOTf. This represents a new type of oxoborane. The stabilization of this oxoborane may be attributed to (1) kinetic stabilization provided by a bulky 3D carboranyl ligand and (2) thermodn. stabilization offered by a carbene ligand. Crystallog. analyses support the presence of the shortest terminal B:O double bond ever reported thus far. Its reactivity has also been examined

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Recommanded Product: Silver(I) trifluoromethanesulfonate. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Redefining the Mechanistic Scenario of Carbon-Sulfur Nucleophilic Coupling via High-Valent Cp*CoIV Species. Author is Lopez-Resano, Sara; Martinez de Salinas, Sara; Garces-Pineda, Felipe A.; Moneo-Corcuera, Andrea; Galan-Mascaros, Jose Ramon; Maseras, Feliu; Perez-Temprano, Monica H..

Mechanism of carbon-sulfur bond formation during reductive elimination of 2-arylpyridine derivative 2-(2-CF3SC6H4)C5H4N from Co(III) half-sandwich cyclometalated 2-phenylpyridine complex [Cp*Co(SCF3)(phpy)] (Hphpy = 2-phenylpyridine) includes activation of Co(III) center by oxidation to Co(IV) with AgSCF3 reagent. The potential access to CoIV species for promoting transformations that are particularly challenging at CoIII still remains underexploited in the context of Cp*Co-catalyzed C-H functionalization reactions. Herein, we disclose a combined exptl. and computational strategy for uncovering the participation of Cp*CoIV species in a Cp*Co-mediated C-S bond-reductive elimination. These studies support the intermediacy of high-valent Cp*Co species in C-H functionalization reactions, under oxidative conditions, when involving nucleophilic coupling partners.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Recommanded Product: Silver(I) trifluoromethanesulfonate. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Pentacyclic Nano-Trefoil. Author is Ju, Huiyeong; Tsuruoka, Yumiko; Hayano, Miho; Lee, Eunji; Park, Ki-Min; Ikeda, Mari; Ishi-i, Jun-ichi; Kuwahara, Shunsuke; Habata, Yoichi.

Tetra-armed cyclen (1) bearing two 4-(4′-pyridyl)benzyl and two 3,5-difluorobenzyl groups and its Ag+ complexes were prepared and structurally characterized. The complexes formed between 1 and Ag+ undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag+/1 molar ratio. It was also revealed that the 3:5 trefoil complex could encapsulate benzene and [D6]benzene selectively in solid-state. The benzene-included structures are stabilized by C-H···F-C interactions between the benzene mol. and the ligand mol.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Related Products of 2923-28-6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about New fluorinated manganese carbonyl complexes for light controlled carbon monoxide (CO) release and the use of bench-top 19F-NMR spectroscopy. Author is Sakla, Rahul; Amilan Jose, D..

CO is used as an essential therapeutic agent. Control delivery and tracking of CO is the important concern for using in therapeutics. The authors report fluorinated Mn(I) tricarbonyl complexes PF-DPA perfluorobenzyl-dipicolinylamine, Mn and CF-DPA·Mn (CF-DPA = trifluoromethylbenzyl-dipicolinylamine) as a new photoCORMs for photo-controlled CO release. For the 1st time, the bench-top 19F-NMR on-off signal was used to monitor light-controlled CO release along with other traditional methods. 19F-NMR signal was initially on which attenuates on irradiating with blue light due to conversion of Mn(I) to Mn(II). CO release behavior of new complexes was also supported by Myoglobin assay, time-dependent IR study and UV-visible experiments Fluorinated Mn carbonyl complexes with 19F-NMR open up vast opportunities for researchers to develop a fast and reliable technique for tracking CO release.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

HPLC of Formula: 2923-28-6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO2-to-CO reduction at low overpotential. Author is Yang, Yong; Ertem, Mehmed Z.; Duan, Lele.

The [fac-Mn(bpy)(CO)3Br] complex is capable of catalyzing the electrochem. reduction of CO2 to CO with high selectivity, moderate activity and large overpotential. Several attempts have been made to lower the overpotential and to enhance the catalytic activity of this complex by manipulating the second-coordination sphere of manganese and using relatively stronger acids to promote the protonation-first pathway. We report herein that the complex [fac-Mn(bpy-CONHMe)(CO)3(MeCN)]+ ([1-MeCN]+; bpy-CONHMe = N-methyl-(2,2′-bipyridine)-6-carboxamide) as a pre-catalyst could catalyze the electrochem. reduction of CO2 to CO with low overpotential and high activity and selectivity. Combined exptl. and computational studies reveal that the amide NH group not only decreases the overpotential of the Mn catalyst by promoting the dimer and protonation-first pathways in the presence of H2O but also enhances the CO2 electroreduction activity by facilitating C-OH bond cleavage, making [1-MeCN]+ an efficient CO2 reduction pre-catalyst at low overpotential.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

COA of Formula: CAgF3O3S. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Trinuclear cationic silver nanoclusters based-on bis-(phosphine) ligands and stabilized by CF3SO3- anions. Author is Han, Chu-Xia; Shao, Zi-Mo; Li, Li; Zhou, Kun; Xue, Chun-Hui; Chen, Bao-Kuan; Ji, Jiu-Yu; Bi, Yan-Feng.

Three trinuclear silver nanoclusters, [Ag3(dppm)3(tBuCC)](CF3SO3)2 (1), [Ag3(dppm)3(CO3)(CH3OH)](CF3SO3)·H2O (2) and [Ag3(dppm)3(Cl)2](CF3SO3)·3DMF (3) (dppm = 1,2-bis-(diphenylphosphino)methane) were obtained and characterized by a series of techniques including single-crystal x-ray diffraction (SCXRD), Fourier transform IR spectrometry (FT-IR), powder x-ray diffraction (PXRD) and thermogravimetric anal. (TGA). In the three compounds, their main body skeletons are made up of similar Ag3 cores shaped in a silver triangle. All the three compounds consist of three silver atoms, three dppm bis-(phosphine) ligands, which are further stabilized by CF3SO3- anions. While the other auxiliary ligands, tBuCC-, CO32- and Cl- are sep. attached to similar Ag3 cores, making them structurally different. Moreover, the luminescence properties, photocurrent responses and electrochem. properties of compounds 1-3 have been investigated. The results indicate that different structures have a very important influence on their properties. The structure-activity relationship of silver cluster materials provides pos. guidance for further design and synthesis of functional silver cluster materials.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Silver(I) trifluoromethanesulfonate(SMILESS: O=S(C(F)(F)F)([O-])=O.[Ag+],cas:2923-28-6) is researched.Electric Literature of C5H5FN2. The article 《A comparative study of [Ag11(iPrS)9(dppb)3]2+ and [Ag15S(sBuS)12(dppb)3]+: templating effect on structure and photoluminescence》 in relation to this compound, is published in Dalton Transactions. Let’s take a look at the latest research on this compound (cas:2923-28-6).

Atomically precise silver clusters with tunable photoluminescence (PL) properties have attracted extensive attention due to their great value for basic science and future applications. Here, we report that the addition of a sulfido template into a triangular thiolated silver cluster [Ag11(iPrS)9(dppb)3]·2CF3SO3·CH3OH (Ag11, dppb = 1,4-bis(diphenylphosphino)butane), which is emissive at 660 nm under ambient conditions, produced another silver cluster [S@Ag15(sBuS)12(dppb)3]·CF3SO3·H2O (Ag15) that displays 716 nm emission with a 56 nm red shift aided by the ligand sec-Bu mercaptan. The sulfido template, which affects the geometrical and electronic structures, results in a red shift of Ag11 room-temperature PL as a result of opening up the template-to-metal charge transfer (TMCT) and disturbing the electronic transition between the metal core and ligands at the periphery.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Maldonado, Tamara; Flores, Erick; Llanos, Leonel; Aravena, Daniel; Vega, Andres; Godoy, Fernando; Aspee, Alexis; Arancibia-Miranda, Nicolas; Ferraudi, Guillermo; Gomez, Alejandra published the article 《Azo-hydrazone tautomerism in organometallic complexes triggered by a -Re(CO)3(L) core: A spectroscopic and theoretical study》. Keywords: azo hydrazone tautomerism rhenium carbonyl organometallic complex; phenyldiazenyl quinolinol rhenium tricarbonyl preparation crystal mol structure tautomerism.They researched the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6 ).Computed Properties of CAgF3O3S. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:2923-28-6) here.

The spectroscopic properties and tautomeric behavior of five novel Rhenium(I) tricarbonyl complexes bearing an azo ligand are presented. The organic ligand is stable in solution as the hydrazone tautomer. It remains as hydrazone in different medium conditions (solvent, concentration, pH, etc.) without the formation of detectable amounts of the azo tautomer. However, the complexation of this ligand to the strong electron-withdrawing fragment -Re(CO)3X (X = Cl-, Br-) causes tautomerism to appear in the organic moiety. Two well-defined regions in the electronic spectra for both tautomers were observed, allowing the azo/enol-keto/hydrazone equilibrium to be followed. TD-DFT calculations indicate that for the keto/hydrazone form, the main absorption band is attributed to an IL transition. In contrast, the azo/enol species shows a major contribution of the 1MLCT (dπ(Re) → dπ*(NN)) transition. The tautomeric equilibrium is easily shifted using solvents with different dielec. constant and hydrogen bond donor/acceptor (HBD/HBA) abilities. Also, the tautomerization process is deeply influenced by the electronic properties of the axial ligand. Therefore, this behavior represents a different strategy for the design of novel materials with optical properties. Furthermore, tautomerism is affected by the concentration of complexes and the presence of water in solvents. The acid-base behavior of these compounds in a 50% volume/volume ethanol-buffer system showed that the azo/enol tautomer is stabilized in acidic media. At the same time, an increase of pH promotes tautomerization toward the keto/hydrazone, followed by forming the anionic form at pH > 8.

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Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Sasaki, Tomoya; Izumi, Reiko; Tsuda, Tetsuya; Kuwabata, Susumu published an article about the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6,SMILESS:O=S(C(F)(F)F)([O-])=O.[Ag+] ).Related Products of 2923-28-6. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:2923-28-6) through the article.

Due to their high conductivity and high physicochem. stability, carbon nanotubes (CNTs) have received a great deal of attention as a promising support material for Pt-based electrode catalysts for redox reactions (ORRs). However, to immobilize Pt nanoparticles (Pt NPs) on their inert surfaces, several CNT pretreatments, including the chem. generation of functional groups and polymer modifications, have been attempted. In this study, we propose a straightforward preparation method for Pt NPs supported on single- and multi-walled carbon nanotubes (SWCNTs and MWCNTs) at room temperature The preparation method includes only two steps: the magnetron sputtering of Pt onto diethylmethylammonium-based protic ionic liquid (IL) and the mixing of the resultant Pt NP-dispersed protic IL with pristine CNTs. Zeta potential measurements reveal that the spontaneous immobilization of the Pt NPs on the CNT surface during the mixing is facilitated by electrostatic interactions between the Pt NPs neg. charged by anion adsorption and the CNTs pos. charged by cation adsorption. The mass activity for the ORR of the Pt NP-modified SWCNTs (Pt-SWCNTs) and MWCNTs (Pt-MWCNTs) prepared using diethylmethylammonium trifluoromethanesulfonate as a medium is approx. 2.5 times higher than that of a com. available electrocatalyst. This high performance is attributable to the small size (ca. 1.9 nm) of Pt NPs with a narrow size distribution and high dispersity on CNTs. In the case of Pt-SWCNTs, surprisingly, the ORR activity is slightly enhanced after 20,000 cycles of an accelerated degradation test because of an unexpected Pt NP shape change from spherical to nanorod-like along the grooves formed at the contacts of the CNTs in the SWCNT bundle. This shape variation and the improvement in catalytic activity will lead to the development of innovative strategies for maintaining electrocatalytic activity over a long period.

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Reference:
Benzofuran – Wikipedia,
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Dunaj, Tobias; Dollberg, Kevin; Ritter, Christian; Dankert, Fabian; von Haenisch, Carsten published the article 《2,6-Diisopropylphenyl-Substituted Bismuth Compounds: Synthesis, Structure, and Reactivity》. Keywords: bismuth isopropylphenyl compound preparation crystal mol structure.They researched the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6 ).Application of 2923-28-6. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:2923-28-6) here.

The 2,6-diisopropylphenyl (Dipp) substituent is introduced to diaryl Bi chem. Dipp2BiBr (1-Br) was prepared by a Grignard reaction and subsequently used as precursor for synthesis of the other diaryl halido bismuthanes Dipp2BiX (1-X, X = F, Cl, I) and the corresponding triflate Dipp2BiOTf (1-OTf). Also, 1,1,2,2-tetrakis(2,6-diisopropylphenyl)dibismuthane (2) was prepared All isolated compounds were characterized via single crystal x-ray diffraction anal., NMR spectroscopy, IR spectroscopy, and elemental anal. Also, the reactivity of a dibismuthane towards elemental S was studied, and the formed dibismuthanyl tri- and pentasulfide (3a, 3b) were characterized by single crystal x-ray anal. Functionalization of the diaryl halido bismuthanes with LiPtBu2 or tBu2PTMS (TMS = SiMe3) gives access to the interpnictogen compound Dipp2Bi-PtBu2 (4), which shows a rare example of a covalent Bi-P bond.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem