COA of Formula: CAgF3O3S. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Trinuclear cationic silver nanoclusters based-on bis-(phosphine) ligands and stabilized by CF3SO3- anions. Author is Han, Chu-Xia; Shao, Zi-Mo; Li, Li; Zhou, Kun; Xue, Chun-Hui; Chen, Bao-Kuan; Ji, Jiu-Yu; Bi, Yan-Feng.
Three trinuclear silver nanoclusters, [Ag3(dppm)3(tBuCC)](CF3SO3)2 (1), [Ag3(dppm)3(CO3)(CH3OH)](CF3SO3)·H2O (2) and [Ag3(dppm)3(Cl)2](CF3SO3)·3DMF (3) (dppm = 1,2-bis-(diphenylphosphino)methane) were obtained and characterized by a series of techniques including single-crystal x-ray diffraction (SCXRD), Fourier transform IR spectrometry (FT-IR), powder x-ray diffraction (PXRD) and thermogravimetric anal. (TGA). In the three compounds, their main body skeletons are made up of similar Ag3 cores shaped in a silver triangle. All the three compounds consist of three silver atoms, three dppm bis-(phosphine) ligands, which are further stabilized by CF3SO3- anions. While the other auxiliary ligands, tBuCC-, CO32- and Cl- are sep. attached to similar Ag3 cores, making them structurally different. Moreover, the luminescence properties, photocurrent responses and electrochem. properties of compounds 1-3 have been investigated. The results indicate that different structures have a very important influence on their properties. The structure-activity relationship of silver cluster materials provides pos. guidance for further design and synthesis of functional silver cluster materials.
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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem