HPLC of Formula: 2923-28-6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO2-to-CO reduction at low overpotential. Author is Yang, Yong; Ertem, Mehmed Z.; Duan, Lele.
The [fac-Mn(bpy)(CO)3Br] complex is capable of catalyzing the electrochem. reduction of CO2 to CO with high selectivity, moderate activity and large overpotential. Several attempts have been made to lower the overpotential and to enhance the catalytic activity of this complex by manipulating the second-coordination sphere of manganese and using relatively stronger acids to promote the protonation-first pathway. We report herein that the complex [fac-Mn(bpy-CONHMe)(CO)3(MeCN)]+ ([1-MeCN]+; bpy-CONHMe = N-methyl-(2,2′-bipyridine)-6-carboxamide) as a pre-catalyst could catalyze the electrochem. reduction of CO2 to CO with low overpotential and high activity and selectivity. Combined exptl. and computational studies reveal that the amide NH group not only decreases the overpotential of the Mn catalyst by promoting the dimer and protonation-first pathways in the presence of H2O but also enhances the CO2 electroreduction activity by facilitating C-OH bond cleavage, making [1-MeCN]+ an efficient CO2 reduction pre-catalyst at low overpotential.
In addition to the literature in the link below, there is a lot of literature about this compound(Silver(I) trifluoromethanesulfonate)HPLC of Formula: 2923-28-6, illustrating the importance and wide applicability of this compound(2923-28-6).
Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem