Category: 2923-28-6

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Inorganic Chemistry called Mole-Ratio-Dependent Reversible Transformation between 2:2 and Cyclic 3:6 Silver(I) Complexes with an Argentivorous Molecule, Author is Ju, Huiyeong; Abe, Tomoko; Takahashi, Yukari; Tsuruoka, Yumiko; Otsuka, Akihiro; Lee, Eunji; Ikeda, Mari; Kuwahara, Shunsuke; Habata, Yoichi, which mentions a compound: 2923-28-6, SMILESS is O=S(C(F)(F)F)([O-])=O.[Ag+], Molecular CAgF3O3S, Related Products of 2923-28-6.

A tetra-armed cyclen (L) with two substituted 3,5-difluorobenzyl and two substituted pyridine-4-yl Me groups at the 1,4- and 7,10-positions of the cyclen ring as side arms was synthesized. When L was reacted with 1 equiv of the silver(I), dimetallo[3.3]paracyclophane-like 2:2 cyclic dimer, [Ag2(L)2](PF6)2, was obtained. The reaction of L with 2 equiv of silver(I) gave a 3:6 cyclic trimer, [Ag6(L)3(CH3CN)3](OTf)6·3CH3CN. Furthermore, reversible complexation between the 2:2 cyclic dimer and 3:6 cyclic trimer was confirmed by 1H NMR and the CSI mass in the addition of silver(I) or the [2.2.2]cryptand.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Related Products of 2923-28-6. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Alternative Synthesis and Structural Analysis of the Antioxidant and Antitumor Agent 2-(3,5-Dimethoxyphenyl)-2,3-Dihydroquinolin-4(1H)-One. Author is Parry, Christopher S.; Grossmann, Matthew D.; Thomas, Amy; Majireck, Max M.; Reinheimer, Eric W.; Kriley, Charles E..

Herein we present the synthesis, structure and NMR and mass spectroscopic analyses of the antioxidant 2-(3,5-dimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one (1), a member of the 2-aryl-2,3-dihydroquinolin-4(1H)-one family of mols. that have been shown to display a range of potent biol. properties. The title mol., prepared by an alternative methodol. to that recently reported, crystallizes in the centrosym. space group P21/c with unit cell dimensions a = 11.775(17) Å, b = 5.3592(8) Å, c = 22.462(3) Å and β = 96.576(11)β. Close anal. of the solid state structure reveals an array of weak N-H•••O hydrogen bonding as well as C-H•••O, and C-H•••π interactions between the neighboring mols. The presence of 1 was also confirmed via NMR and mass spectroscopic analyses.

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Reference:
Benzofuran – Wikipedia,
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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Tethered CAAC-CAAC dimers: oxidation to persistent radical cations and bridging-unit dependent reactivity/stability of the dications, published in 2021, which mentions a compound: 2923-28-6, mainly applied to cyclic alkyl amino carbene dimer stability oxidation potential, Formula: CAgF3O3S.

Herein, we report tethered cyclic(alkyl)(amino)carbene (CAAC) dimers in which two CAAC-motifs are connected by an ethylene-, trans-1,2-cyclohexylene- and propylene-spacer through their N-centers. The 1-electron oxidized radical cations are isolable, whereas a significant influence of the bridging unit on the chem. reactivity becomes apparent in and with the 2-electron oxidized products.

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Benzofuran – Wikipedia,
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In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Self-healing and shape memory functions exhibited by supramolecular liquid-crystalline networks formed by combination of hydrogen bonding interactions and coordination bonding, published in 2021, which mentions a compound: 2923-28-6, Name is Silver(I) trifluoromethanesulfonate, Molecular CAgF3O3S, Application In Synthesis of Silver(I) trifluoromethanesulfonate.

We here report a new approach to develop self-healing shape memory supramol. liquid-crystalline (LC) networks through self-assembly of mol. building blocks via combination of hydrogen bonding and coordination bonding. We have designed and synthesized supramol. LC polymers and networks based on the complexation of a fork like mesogenic ligand with Ag+ ions and carboxylic acids. Unidirectionally aligned fibers and free-standing films forming layered LC nanostructures have been obtained for the supramol. LC networks. We have found that hybrid supramol. LC networks formed through metal-ligand interactions and hydrogen bonding exhibit both self-healing properties and shape memory functions, while hydrogen-bonded LC networks only show self-healing properties. The combination of hydrogen bonds and metal-ligand interactions allows the tuning of intermol. interactions and self-assembled structures, leading to the formation of the dynamic supramol. LC materials. The new material design presented here has potential for the development of smart LC materials and functional LC membranes with tunable responsiveness.

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Reference:
Benzofuran – Wikipedia,
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Garcia-Romero, Alvaro; Martin-Alvarez, Jose M.; Miguel, Daniel; Wright, Dominic S.; Alvarez, Celedonio M.; Garcia-Rodriguez, Raul published the article 《Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes》. Keywords: pyridyl bismuth antimony ligand preparation crystal mol structure complexation; copper silver complexation supramol bismuth antimony pyridyl.They researched the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6 ).Quality Control of Silver(I) trifluoromethanesulfonate. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:2923-28-6) here.

The use of antimony and bismuth in supramol. chem. has been largely overlooked in comparison to the lighter elements of Group 15, and the coordination chem. of the tripodal ligands [Sb(3-py)3] and [Bi(3-py)3] (L) containing the heaviest p-block element bridgehead atoms has been unexplored. Authors show that these ligands form a common hybrid metal-organic framework (MOF) structure with Cu(I) and Ag(I) (M) salts of weakly coordinating anions (PF6-, SbF6-, and OTf-), composed of a cationic substructure of rhombic cage (M)4(L)4 units linked by Sb/Bi-M bonding. The greater Lewis acidity of Bi compared to Sb can, however, allows anion···Bi interactions to overcome Bi-metal bonding in the case of BF4-, leading to collapse of the MOF structure (which is also seen where harder metals like Li+ are employed). This study therefore provides insight into the way in which the electronic effects of the bridgehead atom in these ligand systems can impact their supramol. chem.

From this literature《Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes》,we know some information about this compound(2923-28-6)Quality Control of Silver(I) trifluoromethanesulfonate, but this is not all information, there are many literatures related to this compound(2923-28-6).

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Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

Computed Properties of CAgF3O3S. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Biliverdin chiral derivatives as chiroptical switches for pH and metal cation sensing.

A series of six optically active derivatives of the bile pigment biliverdin, namely (βS,β’S)-dimethylmesobiliverdin-XIIIα, cyclic esters of linear diols [HO(CH2)nOH] where n = 1-6, have been investigated by vibrational CD (VCD) and d. functional theory (DFT) calculations The results were correlated with the length (n) of the diester belt, the verdin helicity and an M &#x21CC P conformational equilibrium – as previously shown by electronic CD (ECD). Furthermore, ECD spectra have been found to be quite sensitive to solvent nature and pH. TD-DFT calculations of the protonated/deprotonated verdins with n = 1 and 2 diester belts resp. have allowed one, moreover, to explain the spectroscopic data in terms of a change in the M &#x21CC P equilibrium Finally, the set of investigated compounds, together with other chirally functionalized “”non-belted”” biliverdin analogs, has also been found to be sensitive to the presence of metal ions, with which the verdins chelate. On the basis of ECD and VCD data, we propose that the spectroscopic changes observed are consistent with self-association (dimerization) of the verdin mols. promoted by the metal cations, as bolstered by DFT calculations, and for which a dimerization constant of 73 000 M-1 is evaluated. We envision the use of current chiroptical spectroscopies in connection with chiral biliverdin derivatives as natural sensors or probes of the micro-environmental conditions, such as pH or the presence of metal ions.

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Computed Properties of CAgF3O3S. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Stable Radical Cation and Dication of a 1,4-Disilabenzene. Author is Chen, Yilin; Li, Jiancheng; Zhao, Yiling; Zhang, Li; Tan, Gengwen; Zhu, Hongping; Roesky, Herbert W..

The reaction of (LSi:)2 (1; L = PhC(NtBu)2) with 2 equiv of Me3SiC2C2SiMe3 gave (Me3SiC2)2(Me3Si)2C4Si2(L)2 (2). 2 exhibited a 1-electron transfer when treated with 1 equiv of [Ph3C]+[B(C6F5)4]- to yield [(Me3SiC2)2(Me3Si)2C4Si2(L)2]·+[B(C6F5)4]- (3) and Ph3CCPh3, resp. When compound 2 was treated with 2 equiv of AgOSO2CF3 a transfer of two electrons occurred to produce [(Me3SiC2)2(Me3Si)2C4Si2(L)2]2+·2[OSO2CF3]- (4) and elemental Ag. The 1,4-disilabenzene 2 is disclosed of an open-shell singlet diradical character, and 3 and 4 are, resp., the elusive stable radical cation and dication species of the 1,4-disilabenzene (2). Also, 2 reacted with Group 16 elements of O, S, and Se by oxidative addition to form (Me3SiC2)2(Me3Si)2C4Si2(L)2(μ-O2) (5) and (Me3SiC2)2(Me3Si)2C4Si2(L)2(μ-E) (E = S (6) and Se (7)), resp.

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Anionic Boron- and Carbon-Based Hetero-Diradicaloids Spanned by a p-Phenylene Bridge, published in 2021-03-17, which mentions a compound: 2923-28-6, mainly applied to anionic boron carbon based hetero diradicaloid phenylene bridge, Recommanded Product: Silver(I) trifluoromethanesulfonate.

Herein we report the synthesis and characterization of anionic boron- and carbon-based Kekulé diradicaloids spanned by a p-phenylene bridge. In contrast to Thiele’s hydrocarbon, a closed-shell singlet system, they show an appreciable population of the triplet state at room temperature, as evidenced by both NMR and EPR spectroscopy. Moreover, en route to these anionic boron- and carbon-based hetero-diradicaloids, the formation of an isolable diamino(4-diarylboryl-phenyl)methyl radical was observed

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The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6 ) is researched.Electric Literature of CAgF3O3S.Han, Jingqi; Cheng, Shun-Cheung; Yiu, Shek-Man; Tse, Man-Kit; Ko, Chi-Chiu published the article 《Luminescent monomeric and dimeric Ru(II) acyclic carbene complexes as selective sensors for NH3/amine vapor and humidity》 about this compound( cas:2923-28-6 ) in Chemical Science. Keywords: ruthenium acyclic carbene ammonia amine vapor humidity sensor. Let’s learn more about this compound (cas:2923-28-6).

A new class of luminescent bis(bipyridyl) Ru(II) pyridyl acyclic carbene complexes with environmentally-sensitive dimerization equilibrium have been developed. Owing to the involvement of the orbitals of the diaminocarbene ligand in the emissive excited state, the phosphorescence properties of these complexes are strongly affected by H-bonding interactions with various H-bonding donor/acceptor mols. With the remarkable differences in the emission properties of the monomer, dimer, and H-bonded amine adducts together with the change of the dimerization equilibrium, these complexes can be used as luminescent gas sensors for humidity, ammonia, and amine vapors. With the responses to amines and humidity and the corresponding change in the luminescence properties, a proof-of-principle for binary optical data storage with a reversible concealment process has been described.

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Design, synthesis, and photophysical properties of Re(I) tricarbonyl 1,10-phenanthroline complexes, published in 2021-01-05, which mentions a compound: 2923-28-6, mainly applied to preparation crystal structure rhenium tricarbonyl phenanthroline complex; luminescence cyclic voltammetry rhenium tricarbonyl phenanthroline complex, Formula: CAgF3O3S.

A series of [Re(5-R-phen)(CO)3(X)]0/+, where phen = 1,10-phenanthroline, R = H, CN, COOH, COONH2, and X = Cl or pyridine, was prepared and characterized by elemental analyses, NMR, visible/UV, emission and cyclic voltammetry. The complexes absorb in the near-UV region of the spectrum, emit between 550 and 600 nm with emission lifetimes between 150 and 500 ns, undergo irreversible oxidation at 1.45 V and a reversible reduction of the 1,10-phenanthroline ligand near -1.30 V vs. Ag/AgCl in acetonitrile.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem