Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 2923-28-6, is researched, SMILESS is O=S(C(F)(F)F)([O-])=O.[Ag+], Molecular CAgF3O3SJournal, Article, Dalton Transactions called The effect of sodium thiosulfate on cytotoxicity of a diimine Re(I) tricarbonyl complex, Author is Capper, Miles S.; Enriquez Garcia, Alejandra; Lai, Barry; Wang, Baiwen O.; Gelfand, Benjamin S.; Shemanko, Carrie S.; Jalilehvand, Farideh, the main research direction is crystal structure rhenium bipyridine thiosulfate carbonyl; rhenium bipyridine thiosulfate carbonyl preparation breast cancer cytotoxicity.Application In Synthesis of Silver(I) trifluoromethanesulfonate.
Recently, diimine Re(I) tricarbonyl complexes have attracted great interest due to their promising cytotoxic effects. Here, the authors compare the cytotoxicity and cellular uptake of two Re(I) compounds fac-[Re(CO)3(bpy)(H2O)](CF3SO3) (1) and Na(fac-[Re(CO)3(bpy)(S2O3)])·H2O (bpy = 2,2′-bipyridine) (2). The Re-thiosulfate complex in 2 was characterized in two solvated crystal structures {Na(fac-[Re(CO)3(bpy)(S2O3)])·1.75H2O·EtOH}4 (2 + 0.75H2O + EtOH)4 and (fac-[Re(CO)3(bpy)(H2O)]) (fac-[Re(CO)3(bpy)(S2O3)])·4H2O (3). The cytotoxicity of 1 and 2 was tested in the MDA-MB-231 breast cancer cell line and compared with that of cisplatin. The cellular localization of the Re(I) complexes was studied using synchrotron-based x-ray fluorescence microscopy (XFM). Replacement of the aqua ligand with thiosulfate renders the complex less toxic most likely by disrupting its cellular entry. Therefore, thiosulfate could potentially have a similar chemoprotective effect against diimine fac-Re(CO)3 complexes as it has against cisplatin.
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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem