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Application In Synthesis of Isobenzofuran-1(3H)-one. In 2019 GREEN CHEM published article about GRAPHITIC CARBON NITRIDE; PHOTOREDOX CATALYSIS; ALPHA-OXYGENATION; MOLECULAR-OXYGEN; SINGLET OXYGEN; BOND-CLEAVAGE; OXIDATION; ETHERS; COPPER; EFFICIENT in [Geng, Pengxin; Hu, Jinchuan] Chongqing Normal Univ, Coll Chem, Chongqing 401331, Peoples R China; [Geng, Pengxin; Tang, Yurong; Pan, Guangtong; Cai, Yunfei] Chongqing Univ, Sch Chem & Chem Engn, 174 Shazheng St, Chongqing 400030, Peoples R China; [Geng, Pengxin; Tang, Yurong; Pan, Guangtong; Cai, Yunfei] Chongqing Univ, Chongqing Key Lab Theoret & Computat Chem, 174 Shazheng St, Chongqing 400030, Peoples R China; [Wang, Wentao] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China in 2019, Cited 80. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2.

A metal-free heterogeneous photocatalytic system has been developed for highly efficient benzylic C-H oxygenations using oxygen as an oxidant. This visible light mediated oxidation reaction utilizes graphitic carbon nitride (g-C3N4) as a recyclable, nontoxic and low cost photocatalyst. Mild reaction conditions allow for the generation of synthetically and biologically valued isochromannones, phthalides, isoquinolinones, isoindolinones and xanthones from readily accessible alkyl aromatic precursors in good yields. The heterogeneous nature of the g-C3N4 catalytic system enables easy recovery and recycling as well as the use in multiple runs without loss of activity. The synthetic utility of this green methodology was further demonstrated by applying in bioactive and drug valued target syntheses.

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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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SDS of cas: 87-41-2. About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Stecoza, CE; Draghici, C; Caproiu, MT; Pircalabioru, GG; Marutescu, L or concate me.

Recently I am researching about DRUG; ANTIBACTERIAL; DISCOVERY, Saw an article supported by the . SDS of cas: 87-41-2. Published in SOC STIINTE FARMACEUTICE ROMANIA in BUCURESTI ,Authors: Stecoza, CE; Draghici, C; Caproiu, MT; Pircalabioru, GG; Marutescu, L. The CAS is 87-41-2. Through research, I have a further understanding and discovery of Isobenzofuran-1(3H)-one

Considering the anti-infective potential of compounds containing the dibenzothiepine scaffold, we set out to obtain new compounds bearing this structure. The synthesized compounds were characterized by spectral studies and elemental analysis and screened for their microbiostatic/microbicidal and antibiofilm properties against reference and clinical microbial strains. The new compounds exhibited a broad spectrum of antimicrobial activity, which was more intensive for the S-oxidized compounds. Some of the compounds also inhibited the ability of the investigated strains to form biofilms on the inert substratum.

SDS of cas: 87-41-2. About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Stecoza, CE; Draghici, C; Caproiu, MT; Pircalabioru, GG; Marutescu, L or concate me.

Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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Recommanded Product: 87-41-2. In 2019 ORG CHEM FRONT published article about PALLADIUM-CATALYZED CARBONYLATION; METAL-FREE CONSTRUCTION; ARYL HALIDES; N-FORMYLSACCHARIN; EX-SITU; CO; HYDROESTERIFICATION; AMINOCARBONYLATION; ALKYNES; SEQUENCE in [Chen, Dianpeng; Yao, Jinzhong; Chen, Linlin; Hu, Linfeng; Zhou, Hongwei] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Zhejiang, Peoples R China; [Chen, Dianpeng] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China; [Li, Xiaofang] Hunan Univ Sci Technol, Sch Chem & Chem Engn, Xiangtan 411201, Hunan, Peoples R China in 2019, Cited 52. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2.

A highly efficient palladium-catalyzed TBD-formate system for carbonylation/hydrogenation was reported. Based on the obvious solvent effect and reasonable mechanism study, we achieved tunable carbonylation or hydrogenation. With the advantages of simple operation, mild conditions and storable reagents, this protocol should be of interest not only for synthetic scientists but also helpful for laboratory operators.

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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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Recommanded Product: Isobenzofuran-1(3H)-one. About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Collin, DE; Folgueiras-Amador, AA; Pletcher, D; Light, ME; Linclau, B; Brown, RCD or concate me.

Recently I am researching about OXIDATIVE ELECTROSYNTHESIS; CUBYL; DECARBOXYLATION; CHEMISTRY; REAGENT; ESTERS; CELL, Saw an article supported by the Engineering and Physical Sciences Research CouncilUK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC) [EP/P013341/1, EP/K039466/1] Funding Source: Medline; Interreg [LabFact: InterReg V project 121] Funding Source: Medline. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Collin, DE; Folgueiras-Amador, AA; Pletcher, D; Light, ME; Linclau, B; Brown, RCD. The CAS is 87-41-2. Through research, I have a further understanding and discovery of Isobenzofuran-1(3H)-one. Recommanded Product: Isobenzofuran-1(3H)-one

The highly strained cubane system is of great interest as a scaffold and rigid linker in both pharmaceutical and materials chemistry. The first electrochemical functionalisation of cubane by oxidative decarboxylative ether formation (Hofer-Moest reaction) was demonstrated. The mild conditions are compatible with the presence of other oxidisable functional groups, and the use of flow electrochemical conditions allows straightforward upscaling.

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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Li, J; Bao, WH; Tang, ZC; Guo, BD; Zhang, SW; Liu, HL; Huang, SP; Zhang, Y; Rao, YJ or concate me.. Name: Isobenzofuran-1(3H)-one

Name: Isobenzofuran-1(3H)-one. Recently I am researching about C-H BONDS; CATALYZED AEROBIC OXIDATION; ELECTRON-TRANSFER REACTIONS; LIGHT PHOTOREDOX CATALYSIS; VISIBLE-LIGHT; SINGLET OXYGEN; METAL-FREE; MOLECULAR-OXYGEN; PHOTOCATALYTIC OXIDATION; KIKUCHII MATSUMOTO, Saw an article supported by the National Key R&D Program of China [2018YFA0901700]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21703036]; Natural Science Foundation of Jiangsu ProvinceNatural Science Foundation of Jiangsu Province [BK20160167]; Thousand Talents Plan (Young Professionals); Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [JUSRP51712B]; Postdoctoral Foundation in Jiangsu Province [2018K153C]; National First-class Discipline Program of Light Industry Technology and Engineering [LITE2018-14]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Li, J; Bao, WH; Tang, ZC; Guo, BD; Zhang, SW; Liu, HL; Huang, SP; Zhang, Y; Rao, YJ. The CAS is 87-41-2. Through research, I have a further understanding and discovery of Isobenzofuran-1(3H)-one

The development of an efficient system for selective oxidation of organic compounds to generate more valuable compounds with molecular oxygen is a significant challenge in industrial chemistry. Bioinspired by the ability of naturally occurring perylenequinonoid pigments (PQPs) to generate reactive oxygen species (ROS) upon photoirradiation, here we report that cercosporin, one of the perylenequinonoid pigments, can function as a cost-effective and environmentally friendly photocatalyst for a wide range of selective oxidations, including benzylic C-H bonds to carbonyls, amines to aldehydes, and sulfides to sulfoxides. All of the representative reactions proceeded smoothly with high efficiency under mild conditions. Owing to the use of inexpensive metal-free visible light-driven photocatalyst produced from microbial fermentation with cheap glucose as the starting material and the ease of handling, we expect that this developed method will be particularly attractive for many more applications in synthetic transformation.

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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Ovchinnikov, MY; Antipin, VA; Khursan, SL or concate me.. Application In Synthesis of Isobenzofuran-1(3H)-one

Application In Synthesis of Isobenzofuran-1(3H)-one. In 2020 J LUMIN published article about BASIS-SET; PHTHALIDE); POLYMERS; THERMOLUMINESCENCE; MODEL; ELECTROLUMINESCENCE in [Ovchinnikov, Mikhail Yu; Antipin, Vyacheslav A.; Khursan, Sergey L.] Ufa Inst Chem UFRC RAS, 71 Prospect Oktyabrya, Ufa 450054, Russia in 2020, Cited 59. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2.

Kinetics of thermostimulated luminescence (TSL) of poly(diphenylenephthalide) (PDPh) films has been studied using mathematical modelling and DFT approximation. TSL of PDPh-film was considered to be arising from irradiative deactivation of diphenylene (DP) fragment of polymer chain in excited state formed upon recombination of the spatial separated ion-radical pairs generated by photoexcitation. Two parallel monomolecular transformations leading to excited DP have been revealed: the first path is characterized by the activation parameters of the kinetic rate constant k1 which equal to Al ti 105 sec 1 and Eat ti 70 kJ mol(-1). This path may be interpreted in terms of mechanical relaxation theory by segmental polymer mobility as electron transfer (ET) from phthalide (Ph) anion-to DP cation-radical. The second channel is supposed to be consist of two consecutive ET from triarylmethyl anion-radical to phthalide neutral (A2 ti 1 sec 1, Ea2 ti 20 kJ mol(-1)), and then to DP cation-radical (A3 N 104 sec 1, E,3 N 40 kJ mol(-1)) of the polymer chain indicating y- and fl-relaxation, respectively. The revealed mechanistic steps and electron retention efficiency estimated in B97-2/6-311 + G(d,p) approximation for the most probable anion-radicals may point out the key role of domino quantum tunneling in transfer and recombination of charges in PDPh films.

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Reference:
Benzofuran – Wikipedia,
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Name: Isobenzofuran-1(3H)-one. About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Hewage, ANDP; Yao, HL; Nammalwar, B; Gnanasekaran, KK; Lovell, S; Bunce, RA; Eshelman, K; Phaniraj, SM; Lee, MM; Peterson, BR; Battaile, KP; Reitz, AB; Rivero, M or concate me.

An article Small Molecule Inhibitors of the BfrB-Bfd Interaction Decrease Pseudomonas aeruginosa Fitness and Potentiate Fluoroquinolone Activity WOS:000469292300026 published article about PROTEIN-PROTEIN INTERACTIONS; BACTERIOFERRITIN STRUCTURE; IRON-METABOLISM; BINDING; ANTIBIOTICS; FERREDOXIN; RESISTANCE; DYNAMICS; PROMOTES; GALLIUM in [Hewage, Achala N. D. Punchi; Eshelman, Kate] Univ Kansas, Dept Chem, 2030 Becker Dr, Lawrence, KS 66047 USA; [Yao, Huili; Rivero, Mario] Louisiana State Univ, Dept Chem, 229A Choppin Hall, Baton Rouge, LA 70803 USA; [Nammalwar, Baskar; Gnanasekaran, Krishna Kumar; Bunce, Richard A.] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA; [Lovell, Scott] Univ Kansas, Prot Struct Lab, 2034 Becker Dr, Lawrence, KS 66047 USA; [Phaniraj, Sahishna M.; Lee, Molly M.; Peterson, Blake R.] Univ Kansas, Dept Med Chem, 2034 Becker Dr, Lawrence, KS 66047 USA; [Battaile, Kevin P.] Hauptman Woodward Med Res Inst, IMCA CAT, 9700 South Cass Ave,Bldg 435A, Argonne, IL 60439 USA; [Reitz, Allen B.] Fox Chase Chem Divers Ctr Inc, 3805 Old Easton Rd, Doylestown, PA 18902 USA; [Nammalwar, Baskar] 10522 Parkdale Ave, San Diego, CA 92126 USA; [Gnanasekaran, Krishna Kumar] 4591 Gatineau Ave, Mississauga, ON L4Z 2R9, Canada; [Eshelman, Kate] 10 Waterview Blvd, Parsippany, NJ 07054 USA; [Lee, Molly M.] NCI, Hatfield CRC, Bldg 10, Bethesda, MD 20892 USA in 2019, Cited 60. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2. Name: Isobenzofuran-1(3H)-one

The iron storage protein bacterioferritin (BfrB) is central to bacterial iron homeostasis. The mobilization of iron from BfrB, which requires binding by a cognate ferredoxin (Bfd), is essential to the regulation of cytosolic iron levels in P. aeruginosa. This paper describes the structure-guided development of small molecule inhibitors of the BfrB-Bfd protein-protein interaction. The process was initiated by screening a fragment library and followed by obtaining the structure of a fragment hit bound to BfrB. The structural insights were used to develop a series of 4-(benzylamino)- and 4-((3-phenylpropyl)amino)-isoindoline-1,3-dione analogs that selectively bind BfrB at the Bfd binding site. Challenging P. aeruginosa cells with the 4-substituted isoindoline analogs revealed a dose-dependent growth phenotype. Further investigation determined that the analogs elicit a pyoverdin hyperproduction phenotype that is consistent with blockade of the BfrB-Bfd interaction and ensuing irreversible accumulation of iron in BfrB, with concomitant depletion of iron in the cytosol. The irreversible accumulation of iron in BfrB prompted by the 4-substituted isoindoline analogs was confirmed by visualization of BfrB-iron in P. aeruginosa cell lysates separated on native PAGE gels and stained for iron with Ferene S. Challenging P. aeruginosa cultures with a combination of commercial fluoroquinolone and our isoindoline analogs results in significantly lower cell survival relative to treatment with either antibiotic or analog alone. Collectively, these findings furnish proof of concept for the usefulness of small molecule probes designed to dysregulate bacterial iron homeostasis by targeting a protein-protein interaction pivotal for iron storage in the bacterial cell.

Name: Isobenzofuran-1(3H)-one. About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Hewage, ANDP; Yao, HL; Nammalwar, B; Gnanasekaran, KK; Lovell, S; Bunce, RA; Eshelman, K; Phaniraj, SM; Lee, MM; Peterson, BR; Battaile, KP; Reitz, AB; Rivero, M or concate me.

Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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An article Small Molecule Inhibitors of the BfrB-Bfd Interaction Decrease Pseudomonas aeruginosa Fitness and Potentiate Fluoroquinolone Activity WOS:000469292300026 published article about PROTEIN-PROTEIN INTERACTIONS; BACTERIOFERRITIN STRUCTURE; IRON-METABOLISM; BINDING; ANTIBIOTICS; FERREDOXIN; RESISTANCE; DYNAMICS; PROMOTES; GALLIUM in [Hewage, Achala N. D. Punchi; Eshelman, Kate] Univ Kansas, Dept Chem, 2030 Becker Dr, Lawrence, KS 66047 USA; [Yao, Huili; Rivero, Mario] Louisiana State Univ, Dept Chem, 229A Choppin Hall, Baton Rouge, LA 70803 USA; [Nammalwar, Baskar; Gnanasekaran, Krishna Kumar; Bunce, Richard A.] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA; [Lovell, Scott] Univ Kansas, Prot Struct Lab, 2034 Becker Dr, Lawrence, KS 66047 USA; [Phaniraj, Sahishna M.; Lee, Molly M.; Peterson, Blake R.] Univ Kansas, Dept Med Chem, 2034 Becker Dr, Lawrence, KS 66047 USA; [Battaile, Kevin P.] Hauptman Woodward Med Res Inst, IMCA CAT, 9700 South Cass Ave,Bldg 435A, Argonne, IL 60439 USA; [Reitz, Allen B.] Fox Chase Chem Divers Ctr Inc, 3805 Old Easton Rd, Doylestown, PA 18902 USA; [Nammalwar, Baskar] 10522 Parkdale Ave, San Diego, CA 92126 USA; [Gnanasekaran, Krishna Kumar] 4591 Gatineau Ave, Mississauga, ON L4Z 2R9, Canada; [Eshelman, Kate] 10 Waterview Blvd, Parsippany, NJ 07054 USA; [Lee, Molly M.] NCI, Hatfield CRC, Bldg 10, Bethesda, MD 20892 USA in 2019, Cited 60. Recommanded Product: Isobenzofuran-1(3H)-one. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2

The iron storage protein bacterioferritin (BfrB) is central to bacterial iron homeostasis. The mobilization of iron from BfrB, which requires binding by a cognate ferredoxin (Bfd), is essential to the regulation of cytosolic iron levels in P. aeruginosa. This paper describes the structure-guided development of small molecule inhibitors of the BfrB-Bfd protein-protein interaction. The process was initiated by screening a fragment library and followed by obtaining the structure of a fragment hit bound to BfrB. The structural insights were used to develop a series of 4-(benzylamino)- and 4-((3-phenylpropyl)amino)-isoindoline-1,3-dione analogs that selectively bind BfrB at the Bfd binding site. Challenging P. aeruginosa cells with the 4-substituted isoindoline analogs revealed a dose-dependent growth phenotype. Further investigation determined that the analogs elicit a pyoverdin hyperproduction phenotype that is consistent with blockade of the BfrB-Bfd interaction and ensuing irreversible accumulation of iron in BfrB, with concomitant depletion of iron in the cytosol. The irreversible accumulation of iron in BfrB prompted by the 4-substituted isoindoline analogs was confirmed by visualization of BfrB-iron in P. aeruginosa cell lysates separated on native PAGE gels and stained for iron with Ferene S. Challenging P. aeruginosa cultures with a combination of commercial fluoroquinolone and our isoindoline analogs results in significantly lower cell survival relative to treatment with either antibiotic or analog alone. Collectively, these findings furnish proof of concept for the usefulness of small molecule probes designed to dysregulate bacterial iron homeostasis by targeting a protein-protein interaction pivotal for iron storage in the bacterial cell.

Recommanded Product: Isobenzofuran-1(3H)-one. About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Hewage, ANDP; Yao, HL; Nammalwar, B; Gnanasekaran, KK; Lovell, S; Bunce, RA; Eshelman, K; Phaniraj, SM; Lee, MM; Peterson, BR; Battaile, KP; Reitz, AB; Rivero, M or concate me.

Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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I found the field of Chemistry very interesting. Saw the article Oxidative Kinetic Resolution of Cyclic Benzylic Ethers published in 2021. Recommanded Product: Isobenzofuran-1(3H)-one, Reprint Addresses Liu, L (corresponding author), Shandong Univ, Sch Pharmaceut Sci, Jinan 250100, Peoples R China.; Liu, L (corresponding author), Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.. The CAS is 87-41-2. Through research, I have a further understanding and discovery of Isobenzofuran-1(3H)-one

A manganese-catalyzed oxidative kinetic resolution of cyclic benzylic ethers through asymmetric C(sp(3))-H oxidation is reported. The practical approach is applicable to a wide range of 1,3-dihydroisobenzofurans bearing diverse functional groups and substituent patterns at the alpha position with extremely efficient enantiodiscrimination. The generality of the strategy was further demonstrated by efficient oxidative kinetic resolution of another type of five-membered cyclic benzylic ether, 2,3-dihydrobenzofurans, and six-membered 6H-benzo[c]chromenes. Direct late-stage oxidative kinetic resolution of bioactive molecules that are otherwise difficult to access was further explored.

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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem

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Authors Tian, XZ; Cheng, XQ; Yang, XZ; Ren, YL; Yao, KS; Wang, HY; Wang, JJ in ROYAL SOC CHEMISTRY published article about METAL-FREE; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; GRAPHENE OXIDE; IONIC LIQUID; FUNCTIONALIZATION; ACTIVATION; KETONES; AIR; DEHYDROGENATION in [Tian, Xinzhe] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China; [Wang, Huiyong; Wang, Jianji] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China; [Tian, Xinzhe; Cheng, Xinqiang; Ren, Yun-Lai; Yao, Kaisheng] Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Henan, Peoples R China; [Yang, Xinzheng] Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci,Inst Chem, Beijing 100190, Peoples R China in 2019, Cited 84. Recommanded Product: 87-41-2. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2

Catalyst-free, additive-free and light-free aerobic conversion of benzylic C-H to C?O bonds is reported. A series of C-H bonds in diphenylmethanes and benzyl ethers underwent this transformation to give the targeted products in low to high yields. The reaction mechanism was also investigated using radical trapping, DFT calculations and O-18-labelled experiments, and the results suggested that the present reaction relied on an activation of oxygen by the bond of the benzene ring.

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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem