The important role of 2,2-Dimethyl-2,3-dihydrobenzofuran-7-ol

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1563-38-8, Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1563-38-8, Name is 2,2-Dimethyl-2,3-dihydrobenzofuran-7-ol

Titanium and zirconium benzofuranoxides. Crystal structures and catalytic properties

Reactions of Ti(OiPr)4 or Zr(OEt)4 with 4 equivalents of 2,3-dihydro-2,2-dimethyl-7-benzofuranol (ddbfoH) in toluene gave neutral complexes that in the solid state are dimers of [Ti(mu-ddbfo) 2(ddbfo)6] and [Zr(ddbfo)3(EtOH)(mu-EtO)] 2 composition. The former could also be conveniently synthesized in a direct reaction of TiCl4 with ddbfoH. This air-stable aryloxo compound was found to initiate living ring-opening polymerization of lactides affording polyesters with narrow molecular weight distribution. It also catalyzed addition of terminal acetylenes to aryl aldehydes. The Royal Society of Chemistry.

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Reference£º
Benzofuran – Wikipedia,
Benzofuran | C8H2379O – PubChem