56786-63-1, Name is (2AR,2’R,4S,5’R,6aR,6bS,8aS,8bR,9S,11aS,12aS,12bS)-2a,4-dihydroxy-5′,6a,8a,9-tetramethylicosahydrospiro[naphtho[2′,1′:4,5]indeno[2,1-b]furan-10,2′-pyran]-2(11aH)-one, molecular formula is C27H42O5, belongs to dioxoles compound, is a common compound. In a patnet, author is NEMOTO, H, once mentioned the new application about 56786-63-1, Recommanded Product: (2AR,2’R,4S,5’R,6aR,6bS,8aS,8bR,9S,11aS,12aS,12bS)-2a,4-dihydroxy-5′,6a,8a,9-tetramethylicosahydrospiro[naphtho[2′,1′:4,5]indeno[2,1-b]furan-10,2′-pyran]-2(11aH)-one.
A NOVEL-APPROACH TO QUATERNARY SUBSTITUTED CHIRAL CYCLOBUTANES – A FORMAL ENANTIOSELECTIVE TOTAL SYNTHESIS OF 1,3-DIOXOLE PHEROMONE, (-)-FRONTALIN
A novel synthesis of the quaternary substituted chiral cyclobutanone (9) was achieved by the concerted ring expansion of the chiral cyclopropyl epoxide (8) which lead to a formal total synthesis of (-)-frontalin (14).
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem