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A nitrogen-directed regioselective homocoupling reaction of aromatic compounds has been found to be catalyzed by a ruthenium complex in the presence of methallyl acetate as a hydrogen scavenger.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H2633O – PubChem

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An efficient N-arylation of heterocycles with aryl-, heteroaryl-, and vinylboronic acids catalyzed by copper fluorapatite

N-Arylation of N-containing heterocycles, such as pyrazoles, imidazoles, and benzimidazoles with aryl-, heteroaryl-, and vinylboronic acids was efficiently carried out by copper fluorapatite (CuFAP) catalyst in MeOH at room temperature under base-free conditions. The N-arylated heterocycles were isolated in good-to-excellent yields.

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Reference£º
Benzofuran – Wikipedia,
Benzofuran | C8H2620O – PubChem

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Ortho-allylation of 1-arylpyrazoles with allyl phenyl ether via iron-catalyzed C-H bond activation under mild conditions

An iron salt and a bipyridine-type ligand catalyze the ortho-allylation of 1-arylpyrazoles and congeners with allyl phenyl ether under mild conditions (0 C). The ligand, an organozinc base, and the nature of the allylating reagent are crucial for the success of this reaction. Under these conditions, a competitive phenylation reaction is largely retarded, and cross-coupling of the organozinc with the allyl electrophile is minimized. The reaction may proceed via iron-catalyzed ortho C-H activation to form a metallic intermediate, which then reacts with the allyl ether in a gamma selective fashion.

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Reference£º
Benzofuran – Wikipedia,
Benzofuran | C8H2608O – PubChem

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Ortho-selective arylation of arylazoles with aryl bromides catalyzed by ruthenium complexes

Ortho-selective direct arylation of arylazoles with aryl bromides has been accomplished in the presence of a catalytic amount of ruthenium complexes. Copyright

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Benzofuran – Wikipedia,
Benzofuran | C8H2632O – PubChem

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Assisted ruthenium-catalyzed C-H bond activation: Carboxylic acids as cocatalysts for generally applicable direct arylations in apolar solvents

(Chemical Equation Presented) Catalytic amounts of aromatic carboxylic acid MesCO2H enabled efficient ruthenium-catalyzed direct arylations in apolar solvents with unparalleled broad scope via a concerted deprotonation-metalation mechanism.

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Benzofuran – Wikipedia,
Benzofuran | C8H2604O – PubChem

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Ruthenium-catalyzed direct ortho-alkynylation of arenes with chelation assistance

The ruthenium-catalyzed direct alkynylation of arenes with the chelation assistance of nitrogen-containing heterocycles including pyridine, pyrimidine, pyrazole, and imidazole are described. The alkynylation is successful even in the presence of an acidic N-H bond. Broad compatibility with functional groups is observed under catalytic conditions. The obtained alkynylated products could serve as precursors for polycyclic heteroarenes. Copyright

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Benzofuran – Wikipedia,
Benzofuran | C8H2606O – PubChem

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Copper-catalyzed arylation of nitrogen heterocycles from anilines under ligand-free conditions

The arylation of pyrazole and derivatives can be achieved by coupling arenediazonium species (formed in situ from anilines) by using a catalytic system that employs low-toxicity and inexpensive copper metal under very mild and ligand-free conditions (T = 20 C). From other nitrogen heterocycles, the presence of an additive (NBu4I) significantly improves the efficiency of the catalytic system. These results represent the first examples of C-N bond formation from arenediazonium species.

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Benzofuran – Wikipedia,
Benzofuran | C8H2641O – PubChem

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Ruthenium-catalyzed C-H bond functionalizations of 1,2,3-Triazol-4-yl- substituted arenes: Dehydrogenative couplings versus direct arylations

The chemoselectivity of ruthenium-catalyzed C-H bond arylations on triazol-4-yl-substituted arenes was found to depend on the substitution pattern of both substrates. While various aryl chlorides led to products stemming from direct arylations, ortho-substituted aryl halides in combination with ortho-alkylated arenes preferentially resulted in oxidative homo-couplings. Georg Thieme Verlag Stuttgart – New York.

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Benzofuran – Wikipedia,
Benzofuran | C8H2602O – PubChem

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Salen-Cu(II) complex catalysed N-arylation of pyrazole under mild conditions

Three inexpensive and air-/moisture-stable complexes (Salden)Cu (Salden = N, N’-bis(salicylidene)-1,2-dimethylethylenediamine), (Saldch)Cu (Saldch = N, N’-bis(salicylidene)-1,2-cyclohexenediamine), and (Salph)Cu (salph = N, N’-bis(salicylidene)-1,2-phenylenediamine) were synthesised and evaluated as catalysts for the N-arylation of pyrazole with aryl halides. A variety of aryl iodides and bromides underwent coupling with pyrazole, promoted by the (Saldch)Cu complex, in moderate to excellent yields without the protection by an inert gas.

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Benzofuran – Wikipedia,
Benzofuran | C8H2627O – PubChem

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Color tuning of cyclometalated iridium complexes through modification of phenylpyrazole derivatives and ancillary ligand based on ab initio calculations

Various iridium complexes consisting of phenylpyrazole (ppz) ligands and isoquinolinecarboxylic acids (iq) as ancillary ligands were designed by energy band-gap calculations via ab initio calculations and synthesized to give rise to various emission wavelengths as expected. Fine color tuning was achieved through varying the position of the methyl substituent on the phenylpyrazole moiety with HOMO electron densities. Additional color tuning was made possible by altering the LUMO through the use of different ancillary ligands such as 1-isoquinolinecarboxylic acid (liq) and 3-isoquinolinecarboxylic acid (3iq).

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Benzofuran – Wikipedia,
Benzofuran | C8H2622O – PubChem