The origin of a common compound about 2923-28-6

Although many compounds look similar to this compound(2923-28-6)Application In Synthesis of Silver(I) trifluoromethanesulfonate, numerous studies have shown that this compound(SMILES:O=S(C(F)(F)F)([O-])=O.[Ag+]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Application In Synthesis of Silver(I) trifluoromethanesulfonate. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Silver(I) complexes based on diorganoselenium(II) ligands with amino or hydroxo functionalities. Author is David, Maria; Mitea, Raluca; Silvestru, Anca.

The diorganoselenide [Me2C(OH)CH2]2Se (1) was prepared by reacting the in situ obtained Na2Se with 1-chloro-2-methyl-2-propanol. Reactions of 1 and [2-(Me2NCH2)C6H4]2Se (2) with appropriate silver(I) salts in 1:1 molar ratio resulted in metal complexes of type [Ag(X)Se{CH2C(OH)Me2}2] [X = OSO2CF3 (OTf) (3), OClO3 (4)] and [Ag(X)Se{C6H4(CH2NMe2)-2}2] [X = OSO2CF3 (5), ONO2 (6)], resp. The ligand 1 and the silver complexes were investigated by appropriate spectroscopic methods, both in solution and in solid state: multinuclear NMR (1H, 13C, 19F, 77Se), ESI+ mass spectrometry, IR spectroscopy and molar conductivity The metal complexes behave as 1:1 electrolytes in 10-3 MeOH solutions, while in solid state the anionic ligands behave as monodentate moieties. Complexes 4 and 5 were investigated by single-crystal X-ray diffraction. The crystal of 4 contains two similar independent mols., 4a and 4b, for which was observed the migration of one OH hydrogen from ligand 1 to the OClO3 group, thus resulting in [Ag(HClO4)Se{OCCH2Me2}{(OH)CCH2Me2}], where ligand 1 behaves as an O,Se monometallic biconective moiety. In 5 the ligand 2 acts as a N,Se,N monometallic triconective moiety. In both compounds Ag(I) is surrounded by the donor atoms in a trigonal pyramidal coordination geometry. Strong Se → Ag intermol. interactions in 4 resulted in 1D coordination polymers built by 4a and 4b mols., resp., while in the crystal of 5 no interaction between heavy atoms was observed Supramol. networks based on H…O contacts are formed in both compounds

Although many compounds look similar to this compound(2923-28-6)Application In Synthesis of Silver(I) trifluoromethanesulfonate, numerous studies have shown that this compound(SMILES:O=S(C(F)(F)F)([O-])=O.[Ag+]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem