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Pyrolysis and combustion experiments of different refuse constituents were performed in a laboratory scale reactor. Different behaviours of thermal degradations, their relationship with the type of products generated as well as the magnitude of their emissions were studied and compared. The wastes selected in this work have been: PE, EVA, PET, cellulose, kraft lignin, almond shells and MSW. In each run, around 50 mg of the refuse were placed in a sample holder which was slowly moved into a furnace preheated at 850 C. More than 100 compounds, considering carbon oxides, light hydrocarbons and PAHs, have been identified and quantified. Different burning behaviours could be distinguished between plastics and lignocellulosic materials. The amount of volatiles emitted by plastics is higher than that generated by lignocellulosic degradation. The major light hydrocarbons obtained, common to all the refuse decompositions are methane, ethylene, benzene, toluene, acetylene and, in some cases, 1,3-butadiene. In the case of the semivolatile compounds, styrene, indene, naphthalene, methylnaphthalene and acenaphthylene reach the major yields.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H112O – PubChem

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o-Triisopropylsiloxyaryl ketones and aldehydes smoothly reacted with the lithium salt of trimethylsilyldiazomethane to give o-triisopropylsiloxyphenylacetylenes which were easily converted to benzofurans by treatment with tetra-n-butylammonium fluoride. 3-Benzofuranmethanols were also obtained when the reaction was conducted in the presence of carbonyl compounds.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H151O – PubChem

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The BTL (biomass-to-liquid) process is an attractive process that produces liquid biofuels from biomass. The FT (Fisher-Tropsch) process is used to produce synfuels such as diesel and gasoline from gasified biomass. However, the H2S (hydrogen sulfide), COS (carbonyl sulfide) and CO2 (carbon dioxide) in the syngas that are produced from the biomass gasifiers cause a decrease of the conversion efficiency and deactivates the catalyst that is used in the FT process. To remove the acid gases, a pilot-scale methanol absorption tower producing diesel at a rate of 1BPD (barrel per day) was developed, and the removal characteristics of the acid gases were determined. A total operation time of 500h was achieved after several campaigns. The average syngas flow rate at the inlet of methanol absorption tower ranged from 300 to 800L/min. The methanol absorption tower efficiently removed H2S from 30ppmV to less than 1ppmV and COS from 2ppmV to less than 1ppmV with a removal of CO2 from 20% to 5%. The outlet gas composition adhered to the guidelines for FT reactors. No remaining sulfurous components were found, and the tar component was analyzed in the spent methanol after long-term operations.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H272O – PubChem

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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 4265-25-2, name is 2-Methylbenzofuran, introducing its new discovery. name: 2-Methylbenzofuran

Benzofuran derivatives and benzofuransare presented as scaffolds in complex molecules and have attracted much attention and prevalent interest due to their interesting biological activity. They also exist in several numbers of naturally occurring compounds and exhibiting biological activity. In this review, we will try to underscore the reactivity of benzofurans through comprehension and giving a full perspective to the readers.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H135O – PubChem

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A reusable copper-based catalyst system was employed for the direct arylation of electron-rich heteroarenes. Under mild and operationally simple reaction conditions good yields and selectivities were obtained using diaryliodonium salts as coupling partners. A combination of experimental methods including kinetic studies, filtration tests, and a series of analytical tools (TXRF, ICP-MS, SEM, XPS, TEM, EFTEM) provide evidence for catalytically active soluble nanoparticles formed from an amorphous heterogeneous precursor. Mechanistic studies hint at a redox-neutral process which promotes counterion dissociation from the diaryliodonium salt by a copper(II) oxide species.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H308O – PubChem

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The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 4265-25-2 is helpful to your research. Synthetic Route of 4265-25-2

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A new range of heterocyclic ring cis/trans-dihydrodiol derivatives (1B, 3B-8B) obtained from metabolism of monocyclic (1A, 3A) and bicyclic heteroarenes (4A-8A) by Pseudomonas putida UV4, has been isolated and stereo-chemically assigned.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H58O – PubChem

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The hetero-Diels-Alder reactions of enolic ethers generated from methylenation of various esters are described, which allow for the rapid synthesis of various substituted [6,6] aromatic spiroketal skeletons.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H355O – PubChem

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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 4265-25-2, name is 2-Methylbenzofuran, introducing its new discovery. Recommanded Product: 2-Methylbenzofuran

In this study, concentrated enzymatic hydrolysate (EH) from corn stover and ammonium dihydrogen phosphate (ADP) were exploited as feedstocks to prepare a novel environment-friendly plywood adhesive. Firstly, the optimal synthesis conditions of the enzymatic hydrolysate-ammonium dihydrogen phosphate (EHADP) adhesive were investigated, and the results manifested that optimizing mass proportion between EH (solids) and ADP, synthesis temperature and time were 90/10, 100 C and 1 h, respectively. When using EHADP synthesized under optimal synthesis conditions, the wet bond strength of the plywood met the requirements of China National Standard GB/T 9846-2015 (wet shear strength?0.7 MPa). The chemical transformations during synthesis treatment on the uncured EHADP adhesive were analyzed by HPLC and 13C NMR, which showed that the EHADP adhesive was a complex mixture of ketones, monosaccharides, 5-HMF, furfural, deoxyfructosazine, Schiff bases, and amides. In addition, ATR FT-IR and Py-GC/MS were employed to analyze the curing mechanism of EHADP adhesive. The results showed that cured EHADP was formed mainly due to the polymerization of furan compounds, and the network was linked by imine linkages and dimethylene ether bridges. TG and DSC analysis showed that the mass degradation and endothermic reaction occurred at around 135?, indicating the EHADP adhesive which prepared under the optimal synthesis conditions could cured at lower temperature.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H354O – PubChem

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With an interest to enhance the aroma of palm kernel oil (PKO), Viscozyme L, an enzyme complex containing a wide range of carbohydrases, was applied to alter the carbohydrates in palm kernels (PK) to modulate the formation of volatiles upon kernel roasting. After Viscozyme treatment, the content of simple sugars and free amino acids in PK increased by 4.4-fold and 4.5-fold, respectively. After kernel roasting and oil extraction, significantly more 2,5-dimethylfuran, 2-[(methylthio)methyl]-furan, 1-(2-furanyl)-ethanone, 1-(2-furyl)-2-propanone, 5-methyl-2-furancarboxaldehyde and 2-acetyl-5-methylfuran but less 2-furanmethanol and 2-furanmethanol acetate were found in treated PKO; the correlation between their formation and simple sugar profile was estimated by using partial least square regression (PLS1). Obvious differences in pyrroles and Strecker aldehydes were also found between the control and treated PKOs. Principal component analysis (PCA) clearly discriminated the treated PKOs from that of control PKOs on the basis of all volatile compounds. Such changes in volatiles translated into distinct sensory attributes, whereby treated PKO was more caramelic and burnt after aqueous extraction and more nutty, roasty, caramelic and smoky after solvent extraction.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H342O – PubChem

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Ever-increasing energy requirements coupled with the desire to cope with global warming have motivated researchers to look for alternative energy resources. Lignocellulosic biomass is an abundant renewable energy resource which can be exploited to reduce the dependency on fossil fuel resources. Acacia cincinnata and Acacia holosericea are fast-growing tree species which produce large quantities of biomass within short span of time and does not require major agricultural inputs to grow. This study is aimed at the intermediate pyrolysis process of Acacia cincinnata and Acacia holosericea species to produce biofuels such as bio-oil, biochar and gaseous product. Mass balance was done to calculate the yields of different products along with the characterisation of bio-oil and biochar produced. Experiments were carried out in a fixed-bed reactor at the pyrolysis temperature of 500 C, heating rate of 25 C/min and nitrogen gas flowrate of 100 cm3/min for the biomass feedstock having particle size between 0.5 and 1 mm. Comprehensive thermochemical characterisation of biomass samples was carried out prior to pyrolysis experiments. The chemical composition of bio-oil samples produced was determined using Gas Chromatography-Mass Spectroscopy (GC?MS) technique. Ultimate analysis, calorific values, pH values and the ash contents in the bio-oil samples were also determined. Bio-oil produced were reported to be complex mixtures of heterocyclic and phenolic compounds resulting from the thermal degradation of basic components of biomass with the calorific values obtained in the range of 23.46?30.65 MJ/kg. Biochar samples produced in the study were characterised with the help of ultimate analysis, FTIR analysis, calorific values, pH values and SEM and EDX analysis. Properties of biochars indicated suitability for energy as well as other applications such as soil remediation and adsorption purposes. Study revealed a decent potential of Acacia cincinnata and Acacia holosericea species as biofuels resources.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H28O – PubChem