On September 23, 2022, Zhang, Yan; Liu, Wen; Xu, Yuenian; Liu, Yong; Peng, Jiajian; Wang, Minyan; Bai, Ying; Lu, Hua; Shi, Zhuangzhi; Shao, Xinxin published an article.Electric Literature of 60770-67-4 The title of the article was S-(Methyl-d3) Arylsulfonothioates: A Family of Robust, Shelf-stable, and Easily Scalable Reagents for Direct Trideuteromethylthiolation. And the article contained the following:
A family of electrophilic deuterated methylthiolating reagents, S-(Methyl-d3) arylsulfonothioates, was developed in two or three steps from cheap d4-MeOH in high yields. S-(Methyl-d3) arylsulfonothioates represent a kind of powerful deuterated methylthiolating reagent and allow modular (trideuteromethyl)thiolation with a variety of nucleophiles or electrophiles including aryl(hetero) iodides, boronic acids esters, terminal alkynes, β-ketoester, and oxindole under mild reaction conditions. A structure-reactivity research study was conducted and provided a new avenue for the development of deuterated methylthiolating reagents and efficient methodol. for (trideuteromethyl)thiolation. The experimental process involved the reaction of 5-Iodobenzofuran(cas: 60770-67-4).Electric Literature of 60770-67-4
The Article related to structure reactivity trideuteromethylthiolation trideuteromethyl arylsulfonothioate, trideuteromethyl arylsulfonothioate preparation methylthiolation nucleophile electrophile and other aspects.Electric Literature of 60770-67-4
Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem