Yang, Wenjun; Ling, Bo; Hu, Bowen; Yin, Haolin; Mao, Jianyou; Walsh, Patrick J. published an article in 2020, the title of the article was Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Umpolung 1,4-Addition of Aryl Iodides to Enals.Related Products of 60770-67-4 And the article contains the following content:
An umpolung 1,4-addition of aryl iodides to enals promoted by cooperative (terpy)Pd/NHC catalysis was developed that generates various bioactive β,β-diaryl propanoate derivatives This system is not only the first reported palladium-catalyzed arylation of NHC-bound homoenolates but also expands the scope of NHC-induced umpolung transformations. A diverse array of functional groups such as esters, nitriles, alcs., and heterocycles are tolerated under the mild conditions. This method also circumvents the use of moisture-sensitive organometallic reagents. The experimental process involved the reaction of 5-Iodobenzofuran(cas: 60770-67-4).Related Products of 60770-67-4
The Article related to synergistic nitrogen heterocyclic carbene palladium catalyzed umpolung addition, diaryl propanoate preparation addition aryl iodide enal, n-heterocyclic carbenes, addition reactions, cooperative catalysis, palladium, umpolung and other aspects.Related Products of 60770-67-4
Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem