Reference of (R)-Ethyl 4-chloro-3-hydroxybutanoate. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: (R)-Ethyl 4-chloro-3-hydroxybutanoate, is researched, Molecular C6H11ClO3, CAS is 90866-33-4, about Stereochemical control of microbial reduction. 17. A method for controlling the enantioselectivity of reductions with bakers’ yeast. Author is Nakamura, Kaoru; Kawai, Yasushi; Nakajima, Nobuyoshi; Ohno, Atsuyoshi.
The stereoselectivity of the bakers’ yeast-catalyzed reduction of β-keto esters to optically active β-hydroxy esters can be controlled by introducing a 3rd reagent. To gain insight into the mechanism of this enzymic reduction, β-hydroxy ester reductases were isolated from bakers’ yeast. Four dominant competing enzymes were isolated, purified, and characterized. Among these, 2 reduced β-keto esters stereospecifically to the corresponding D-β-hydroxy esters. The other 2 afforded the L-hydroxy esters. The rates of enzymic reduction were determined in the presence and absence of the additives.
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Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem