Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 14400-67-0, Name is 2,5-Dimethylfuran-3(2H)-one, SMILES is O=C1C(C)OC(C)=C1, in an article , author is Chanda, Rupsa, once mentioned of 14400-67-0, Category: benzofurans.
Iron-Catalyzed Functionalization of 3-Benzylideneindoline Through Tandem Csp(2)-Csp(3) Bond Formation/Isomerization with pi-Activated Alcohols
A new synthetic protocol was developed for the selective synthesis of diverse 3-substituted indoles through tandem carbon-carbon bond formation and isomerization of 3-benzylidene-1-tosylindoline by direct use of alcohols as alkylating agents in the presence of catalytic FeCl3. This method is applicable to a wide range of substrates containing varieties of functional groups. Direct use of alcohols, such as benzylic, allylic, and propargylic alcohols, as electrophiles and the use of non-toxic iron catalyst makes this strategy attractive and environmentally benign. A plausible mechanism has also been proposed for this tandem reaction.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 14400-67-0, you can contact me at any time and look forward to more communication. Category: benzofurans.
Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem