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In the present study, eight self-thermochromic fluorans (STC1-STC8) were synthesized, and their reversible thermochromic properties were investigated without the use of a color developer. This work demonstrated the role of the phenol group on ring c on the thermochromic reversibility of the fluorans. Furthermore, the two-component mixtures that contained fluorans and methyl stearate were used to examine the thermochromic behaviors of the fluorans with steady heating and cooling rates. The thermochromic properties of the fluorans were evaluated using solid-state UV-Vis, reflectance and FT-IR spectroscopic techniques. DFT calculations were conducted to justify the optical behaviors of the fluorans in their spirolactam forms (STC1-STC8) and cationic forms (STC1+- STC8+). Finally, STC1 was successfully microencapsulated and applied in acrylic fiber to use as thermal indicators.

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3,3-Bis-(4-dimethylaminophenyl)-6-dimethylaminophthalide is produced by oxidizing an alkali metal salt of 2-[4,4′-bis-(dimethylamino)-benzhydryl]-5-dimethylaminobenzoic acid in an aqueous solution of pH of 8 to 14 with hydrogen peroxide, oxygen or air in the presence of a catalyst selected from the group consisting of cobalt compounds and copper compounds.

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Construction materials play a crucial role in the thermal behaviour of the urban space as well as the building energy consumption and indoor environmental quality. Recently, there has been growing interest in optical construction materials/coatings as an effective method to minimise energy use, improve indoor and outdoor thermal comfort and fight urban overheating. Thermochromic materials as one of the advanced optical materials that change their optical properties/colour as a function of the ambient temperature can present lower/higher surface temperature than conventional materials during the warm/cold periods. Although pilot applications of thermochromic materials in the built environment shown a tremendous energy conservation potential, the serious optical degradation they exhibited, restricts seriously their use. Recent development in the field of thermochromic materials including quantum dots, plasmonics, photonic crystals, conjugated polymers, Schiff bases, liquid crystals, and nano optical filters for Leuco dyes present fascinating and impressive characteristics, enhance significantly the potential of thermochromic materials and opens new opportunities for the development and use of advanced cutting-edge optical materials. The present paper aims to offer a comprehensive overview of the recent developments on advanced thermochromic materials and on their energy conservation potential.

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For the purpose of extending the color-change range of thermochromic materials, the new thermochromic microcapsules (TCMs) were designed by combining thermochromic materials with optimized dispersive-cationic dyes. Three types of TCMs, which displayed three primary colors of red, yellow and blue when exposed to high temperature, were prepared separately. By color matching with three-primary colors, the matched TCMs could present remarkable thermochromic properties. Especially, with the variety of ambient temperature, the colors of the TCMs could change reversibly between different tones and exhibit more gorgeous colors than common thermochromic materials, which made it possible to solve the problem of the narrow color-change range for common thermochromic material. In this paper, the mechanism of expanding thermochromic colors, thermochromic performances, color matching effects and thermal stabilities of the TCMs and the modified fabrics were investigated. The TCMs were of practical significances for developing thermochromic intelligent textiles.

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Objectives: The objective of this study was to investigate the effects of mate tea (MT) [Ilex paraguariensis] on alveolar socket healing after tooth extraction. Materials and methods: Sixteen male rats were divided into MT and control groups. MT was administered by intragastric gavage at a dose of 20 mg/kg/day for 28 days before and 28 days after right maxillary incisor extraction. The control group received an equal volume of water. Histopathological and histometric analysis of the neoformed bone area and osteocyte density were performed, as well as immunohistochemical analysis of osteocalcin (OCN), receptor activator of nuclear factor kappa-B ligand (RANKL), osteoprotegerin (OPG), tartrate-resistant acid phosphatase (TRAP), and manganese superoxide dismutase (MnSOD) in the alveolar socket. Calcium, phosphorus, alkaline phosphatase (ALP) activity, total antioxidant capacity (TAC), and malondialdehyde (MDA) were measured in plasma, whereas TRAP activity was determined in serum. Results: Histometry evidenced an increase in bone area (P < 0.0001) and osteocyte density (P < 0.0001). MT increased immunolabeling of MnSOD (P < 0.001), OCN (P < 0.0001), RANKL (P < 0.001), OPG (P < 0.0001), and TRAP (P < 0.001). Calcium and phosphorus concentrations did not differ between the groups. In addition, MT enhanced ALP (P < 0.05) and TRAP (P < 0.0001) activities. MT increased the TAC (P < 0.001), whereas it reduced MDA concentrations (P < 0.0001). Conclusions: MT increases bone area and osteocyte density in the alveolar socket healing on day 28 after tooth extraction. Clinical relevance: Regular MT ingestion improves the antioxidant defenses and bone formation, which is beneficial for alveolar socket bone healing after tooth extraction. Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 125-20-2. In my other articles, you can also check out more blogs about 125-20-2

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Photolytic and photocatalytic reactions of sarin (GB), soman (GD), sulfur mustard (HD), cyanogen chloride (CK) and perfluoroisobutylene (PFIB) vapors in air were carried out. It was shown that vapors of GB, GD, HD and PFIB could be efficiently eliminated by UV light from germicidal lamp through either photolysis or photocatalysis, but CK could hardly be done through photodegradation. It was demonstrated that GB, GD and HD might possibly undergo a photo-induced polymerization under UV light irradiation. Photocatalytic reaction would lead to a cleavage of these molecules into small inorganic compounds at TiO2 surface. The experimental results strongly suggested that both photolysis and photocatalysis of GB vapor at static conditions were kinetically slowed down and possibly limited by a low diffusion rate of GB molecule. It has been testified that the static photolysis approach could be applicable for decontamination of GB vapor in an indoor space. And that, a dynamic photocatalysis approach for decontamination of GB vapor was proved to be much more efficient than that through photolysis, and it was also considered to be feasible for decontamination of air polluted by GB vapor.

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Pancreatic lipase inhibitory effect of methanolic extract of florets Aster sp. was studied. In case of Aster sp. (White florets) the pancreatic lipase inhibition recorded was 82.75% with an Ic50 value of 38mug/mL. Aster sp. (light pink) showed 80.04 % inhibition with an Ic50 of 72 mug/mL. On 2 h dialysis, both the extracts lost their significant pancreatic lipase inhibitory activity, indicating the reversible nature of inhibition. pH slightly affected the performance of pancreatic lipase inhibitory activity. extract (white florets) also showed 22.03% superoxide radical scavenging activity and 22.73% free radical scavenging activity indicating the multifunctional nature of the extract. Light pink florets showed 40.67% superoxide radical scavenging activity and 24.10% free radical scavenging activity. Saponin and alkaloid molecule in white florets of Aster sp. and alkaloid in light pink florets were identified as active principles for pancreatic lipase inhibitory activity.

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Hyperthermostable alkaline lipase from Bacillus sonorensis 4R was purified and characterized. The enzyme production was carried out at 80C and 9.0 pH in glucose-tween inorganic salt broth under static conditions for 96 h. Lipase was purified by anion exchange chromatography by 12.15 fold with a yield of 1.98%. The molecular weight of lipase was found to be 21.87 KDa by SDS-PAGE. The enzyme activity was optimal at 80C with t 1 / 2 of 150 min and at 90C, 100C, 110C, and 120C; the respective values were 121.59 min, 90.01 min, 70.01 min, and 50 min. The enzyme was highly activated by Mg and t 1 / 2 values at 80C were increased from 150 min to 180 min when magnesium and mannitol were added in combination. The activation energy calculated from Arrhenius plot was 31.102 KJ/mol. At 80-120C, values of Delta H and Delta G were in the range of 28.16-27.83 KJ/mol and 102.79 KJ/mol to 111.66 KJ/mol, respectively. Lipase activity was highest at 9.0 pH and stable for 2 hours at this pH at 80C. Pretreatment of lipase with MgSOand CaSOstimulated enzyme activity by 249.94% and 30.2%, respectively. The enzyme activity was greatly reduced by CoCl CdCl HgCl CuCl Pb(NO PMSF, orlistat, oleic acid, iodine, EDTA, and urea.

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A glassy carbon electrode (GCE) modified with polyaminobenzene sulfonic acid functionalized single-walled carbon nanotubes (f-SWCNT) and electropolymerized aluminon has been developed for the simultaneous determination of naringin and hesperidin. Polyaluminon has been obtained by potentiodynamic electrolysis in basic medium from 100 mumol L?1 monomer solution by 10-fold potential cycling from 0.1 to 0.8 V at potential scan rate of 100 mV s?1. The polyaluminon-based electrode provides a statistically significant increase in the naringin and hesperidin oxidation currents at the same potentials in comparison to the electrode modified with carbon nanotubes. The electrode has been characterized by scanning electron microscopy (SEM) and electrochemical methods. The polyaluminon-modified electrode has demonstrated a 1.5-fold increase in the effective surface area compared to the f-SWCNT/GCE as well as a 2.1-fold lower electron transfer resistance. The electrooxidation parameters of hesperidin and naringin, including the anodic transfer and diffusion coefficients and number of electrons, have been determined. Differential pulse voltammetry in phosphate buffer (PB) pH 5.0 has been employed for the simultaneous determination of naringin and hesperidin. The linear dynamic ranges from 0.10 to 2.5 and 2.5 to 25 mumol L?1 have been obtained for the both analytes with the detection limits of 0.020 and 0.029 mumol L?1 for naringin and hesperidin, respectively. The method has been employed for the analysis of orange and grapefruit juice.

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The pretreatment of the phosphoric acid is a stage of utmost importance leading to an optimal recovery of the uranium present in this acid. To this end, the degradation of the organic matter which obstructs considerably this recovery was tested by gamma irradiation. This study lies within the scope of the radiation/matter interaction; concerning the use of the gamma irradiator as proceed of phosphoric acid purification by the degradation of di butyl phthalate (DBP). Studies of the interaction of gamma radiation with phosphoric acid solutions polluted by an organic matter concern the study of the influence of some parameters such as: dose rate (0.5-35 kGy), initial concentration (50-500 mg/L) of the pollutant, pH and % in P2O5 on the degradation of organic matter by gamma irradiation. The reactions followed pseudo first order kinetics for different initial concentrations. The results made it possible to say that the degradation of di butyl phthalate by gamma irradiation is dependent on the amount of the concentration of DBP and pH. The G-values decreased with absorbed doses, and increased with higher initial concentrations.Purification of phosphoric acid by gamma radiation does not degrade the quality of this acid.

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