Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 4412-91-3, Name is 3-Furanmethanol, molecular formula is C5H6O2, belongs to benzofurans compound, is a common compound. In a patnet, author is Frankowski, Sebastian, once mentioned the new application about 4412-91-3, Application In Synthesis of 3-Furanmethanol.
Deconjugated-Ketone-Derived Dienolates in Remote, Stereocontrolled, Aromative aza-Diels-Alder Cycloaddition
In the manuscript, the application of beta,gamma-unsaturated ketones as precursors of electron-rich dienophiles in the organocatalytic, aromative inverse-electron-demand hetero-Diels-Alder cycloaddition is described. The reaction leads to the formation of biologically relevant benzofuran derivatives bearing additional tetrahydropyridine ring. The reaction is fully site-selective and occurs preferentially at the distal double bond of the dienolate intermediate. Given the absolute configuration assignment a step-wise mechanism has been proposed and the formation of aromatic benzofuran ring indicated as the driving force of the cascade.
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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem