An article Aerobic conversion of benzylic sp3 C- H in diphenylmethanes and benzyl ethers to CvO bonds under catalyst-, additive- and light- free conditions WOS:000463959900008 published article about METAL-FREE; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; GRAPHENE OXIDE; IONIC LIQUID; FUNCTIONALIZATION; ACTIVATION; KETONES; AIR; DEHYDROGENATION in [Tian, Xinzhe] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China; [Wang, Huiyong; Wang, Jianji] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China; [Tian, Xinzhe; Cheng, Xinqiang; Ren, Yun-Lai; Yao, Kaisheng] Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Henan, Peoples R China; [Yang, Xinzheng] Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci,Inst Chem, Beijing 100190, Peoples R China in 2019, Cited 84. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2. Formula: C8H6O2
Catalyst-free, additive-free and light-free aerobic conversion of benzylic C-H to C?O bonds is reported. A series of C-H bonds in diphenylmethanes and benzyl ethers underwent this transformation to give the targeted products in low to high yields. The reaction mechanism was also investigated using radical trapping, DFT calculations and O-18-labelled experiments, and the results suggested that the present reaction relied on an activation of oxygen by the bond of the benzene ring.
Formula: C8H6O2. About Isobenzofuran-1(3H)-one, If you have any questions, you can contact Tian, XZ; Cheng, XQ; Yang, XZ; Ren, YL; Yao, KS; Wang, HY; Wang, JJ or concate me.