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An asymmetric palladium-catalyzed intramolecular oxidative aminoarylation of alkenes has been developed with quinoline?oxazoline chiral ligands and Ag2CO3 as the oxidant. Various indolines containing a quaternary stereogenic center were synthesized in high yield with excellent enantioselectivity. Preliminary mechanistic studies suggest that the addition of a catalytic amount of phenylglyoxylic acid significantly accelerates the reaction and slightly enhances the enantioselectivity.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H3391O – PubChem