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The expected 7-alkoxy-2-methylbenzo[b]furans were effectively given in the CsF-mediated Claisen rearrangement of phenyl propargyl ethers with an o-alkoxy substituent on the benzene ring. On the other hand CsF did not affect the production of the corresponding benzo[b]furans when ethers, carrying a propargyl residue modified by either 1,1-dimethyl or 3-ethoxycarbonyl functions, were used as substrates in the rearrangement.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H150O – PubChem

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In this work, the pyrolysis of furans (furan, 2-methylfuran, furfuryl alcohol, and furfural) have been checked by Py-GC?MS at 1100 C to detect the decomposition of furans and the formation of benzene derivatives and PAH. From the Py-GC?MS results, different side chain functional groups on furan-ring lead to different kinds of products and product distributions, such as hydroxyl group leading to dimers, and aldehyde group leading to pyrans, but the mechanism for furan-ring opening and decomposition is universal for furans pyrolyzed in this study. In order to explain the experimental results and the formation of benzene derivatives and PAH, the formation of benzene from furan has also been calculated by B3LYP/6-31G + +(d,p). Two possible benzene formation mechanisms, Diels-Alder and acetylene reaction mechanism, have been proposed and calculated. By comparison, it has been regarded that Diels-Alder reaction was more possible for PAH formation as this mechanism has a lower activation energy for initiation step, but acetylene reaction mechanism was more possible for benzene formation as this mechanism has a lower global activation energy.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H321O – PubChem

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Chinese quince (Chaenomeles sinensis) is used in food and pharmaceutical products, but it is seldom eaten as a raw fruit due to its astringent, woody flesh. The structural characterization of lignin fractions from Chinese quince was very important to investigate the structure-activity relationships of lignin. In this investigation, to characterize the structure of lignin in Chinese quince fruits, the milled wood lignin sample was isolated from the fruits (FMWL) and the chemical structure of FMWL was investigated by sugar analysis, FT-IR, GPC, pyrolysis-GC/MS analysis, UV spectra analysis, thermogravimetric analysis (TGA), and advanced NMR spectroscopic techniques. In addition, the lignin fraction from the stalk of Chinese quince (SMWL) was also prepared for comparison to obtained more information of lignin structure in the fruits. The results showed that the two lignin fractions isolated from fruit and stalk of Chinese quince exhibited different structural features. The two MWL samples were mainly composed of-O-4 ether bonds,-5 and-0 carbon-carbon linkages in the lignin structural units. Compared to the SMWL, the FMWL fraction had the higher S/G ratio and more carbohydrates linkages. The predominant carbohydrates associated with FMWL and SMWL fractions were glucans-type hemicelluloses and xylan-type hemicelluloses, respectively. Understanding the structure of lignin could give insight into the properties of the lignin and enable the food processing industry to separate lignin more efficiently.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H336O – PubChem

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In recent years, food frauds and adulterations have increased significantly. This practice is motivated by fast economical gains and has an enormous impact on public health, representing an important issue in food science. In this context, this review has been designed to be a useful guide of potential biomarkers of food authenticity and safety. In terms of food authenticity, we focused our attention on biomarkers reported to specify different botanical or geographical origins, genetic diversity or production systems, while at the food safety level, molecular evidences of food adulteration or spoilage will be highlighted. This report is the first to combine results from recent studies in a format that allows a ready overview of metabolites (<1200 Da) and potentially molecular routes to monitor food authentication and safety. This review has therefore the potential to unveil important aspects in food adulteration and safety, contributing to improve the current regulatory frameworks. I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 4265-25-2, help many people in the next few years.Recommanded Product: 2-Methylbenzofuran

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H205O – PubChem

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A new methodology for the construction of methyl-substituted benzofuran rings from the reactions of calcium carbide with salicylaldehyde p-tosylhydrazones/2-hydroxyacetophenone p-tosylhydrazones is described. Various 2-methylbenzofurans and 2,3-dimethylbenzofurans could be obtained in satisfactory yield by using a cuprous chloride catalyst. The advantages of this protocol include the use of a readily available and easy-to-handle acetylene source and simple workup procedure.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H104O – PubChem

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The non-metallic fraction of waste printed circuit boards (PCBs) has received extensive attention for material recycling, due to the potential risk of brominated flame retardants and heavy metals in PCBs. Here, the catalytic pyrolysis of PCBs was performed at 400?600 C in a two-stage fixed bed reactor. Low-cost Fe and Ni metals were investigated for their catalytic effect on the product yields and bromine removal from the pyrolysis products. In the absence of additives, the maximum oil yield of 50.1 wt% was obtained at 500 C from the PCBs pyrolysis. The addition of Ni particles decreased the oil yield to 29.1 wt%, and increased the gas yield to 9.6 wt% at 600 C. The Fe/Ni mixture had a synergistic effect on the product yields, which depended on different pyrolysis temperatures. The composition of the oils from the PCBs pyrolysis was dominated by phenol derivatives. The presence of Fe or Ni particles promoted the formation of phenol and other aromatic compounds, such as benzene and toluene. Moreover, the transformation of bromine species was exhaustively investigated. The higher temperature promoted the conversion of brominated compounds into HBr. Fe particles exhibited excellent debromination performance, which not only reduced the formation of organobromine compounds, but also captured some of the evolved bromine.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H192O – PubChem

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In recent years, increasing eutrophication in large freshwater lakes, which are an important drinking water source for cities in China, have been resulted in substantial cyanobacteria blooms that could cause serious taste and odor (T&O) problems. In this investigation, three typical lakes (Songhua Lake, Chaohu Lake and Taihu Lake) as drinking water sources located in different geographical areas in China, were selected to study the problems of cyanobacteria-derived T&O (i.e., 2-methylisobornoel, geosmin, beta-ionone, 2-isopropyl-3-methoxypyrazine, 2-isobutyl-3-methoxypyrazine, and 2-methylbenzofuran). The occurrence of T&O in target lakes was compared across various nutrition states and geographic locations, to get more information for early warning for algal bloom and T&O occurrence, being useful lake water management and purification. Results show that the occurrence of T&O in Songhua Lake was the poorest for the lowest nutrient state, as a first report in T&O research field in China. This is a lake located in Northeast China at high latitude, with lower water temperatures. The occurrence of T&O in Chaohu Lake was ranked in the middle. That in Taihu Lake was the most intensive. Finally, the relationship between water quality, T&O and its origin was analyzed by multivariate statistical methods (correlation analysis, principal component, and cluster analyses).

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H341O – PubChem

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The conditions used to generate wood smoke for the purpose of smoking food greatly affect the flavor character of the resulting food. The relationships between wood type and smoke generation conditions and the resulting volatile composition and flavor character are not well understood. The objective of this study was to characterize the volatile organic compounds (VOCs) in K?nuka (Kunzea ericoides) wood smoke. Smoke was generated at four temperatures (180?480 C) under either air or nitrogen using a lab-scale smoke generator. VOCs were extracted in-line by stir bar sorptive extraction (SBSE) and analyzed by gas chromatography mass spectrometry (GC?MS). More than three hundred compounds were detected, of which phenols were the dominant class, followed by ketones and aldehydes. Temperature had a greater impact than either air or nitrogen on the VOC profile, however some large compound-specific effects were observed. Comparison of 2,6-dimethylphenol, creosol, furfural, 2-methoxy-4-propylphenol, 2-furanmethanol and 4-hydroxy-3,5-dimethoxybenzaldehyde demonstrated that their intensities varied with the smoke generation temperature under both air and nitrogen, implying that different aroma profiles can be developed.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H349O – PubChem

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Direct one-pot transformation of lignocellulosic biomass has been developed as an effective and sustainable strategy to produce fuel blend stocks and high value chemical building blocks. In this wok, a bi-functional catalyst system consisting of palladium supported on carbon (Pd/C) and metal triflates (i.e., Sm(OTf)3, La(OTf)3, and Cu(OTf)2) were shown to promote the biomass liquefaction in both hot-compressed water and supercritical ethanol medium, converting fir wood into oxygenated compounds. The highest bio-oil yield from hydrothermal liquefaction (HTL) was 10.47 wt% over Pd/C whereas the highest bio-oil yield of 49.71 wt% was achieved from supercritical ethanol liquefaction (SCEL) over the bi-functional catalyst system of Pd/C and La(OTf)3. Higher heating values, carbon recovered values and boiling point distributions were further determined for elucidating the physical properties of the bio-oils. Gas chromatography mass spectrometry (GC?MS) analysis of the bio-oils revealed the chemical composition of the bio-oils. Substituted phenols and cyclopentenone/cyclopentanone type compounds consisted of more than 60 area% of the total products from HTL, whereas phenol and esters represented the major products from SCEL. The major reaction pathways are proposed based on the GC?MS results, which include depolymerizaton, isomerization, dehydration, condensation, and hydrogenation.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H124O – PubChem

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The toxicity of fire effluents is not a material property but a function of both the material and the fire environment. To be meaningful, it is essential that toxicity results should relate to the end-use fire situation. This paper reviews current fire effluent toxicity tests, their relevance to fire, and the ways of assessing and applying their results to reduce fire hazards. There are a large number of different methods for determination of the toxic potency of fire effluents from materials or products. These different methods yield apparently inconsistent data because they represent different fire scenarios; measure product yields either as a function of material flammability or independent of it; base the toxicity assessment on the concentrations of different species; or use animal exposure to generate an overall estimate of toxic potency without knowledge of the relative contributions of the chemical species. The drive for internationally harmonised methods for assessment of combustion toxicity, through adoption of international standards, such as those of ISO, provides the framework for meaningful and appropriate use of toxic potency data in the assessment of fire hazard. As structures and means of transportation become larger and more complex, there is movement away from the more traditional methods of ensuring fire safety by prescriptive codes, towards fire risk assessments and engineering solutions. Reliable rate of heat release, fire effluent toxicity and smoke generation data are all essential elements of such an assessment.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H144O – PubChem