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Biomass burning is a large source of volatile organic compounds (VOCs) and many other trace species to the atmosphere, which can act as precursors to secondary pollutants such as ozone and fine particles. Measurements performed with a proton-transfer-reaction time-of-flight mass spectrometer during the FIREX 2016 laboratory intensive were analyzed with positive matrix factorization (PMF), in order to understand the instantaneous variability in VOC emissions from biomass burning, and to simplify the description of these types of emissions. Despite the complexity and variability of emissions, we found that a solution including just two emission profiles, which are mass spectral representations of the relative abundances of emitted VOCs, explained on average 85% of the VOC emissions across various fuels representative of the western US (including various coniferous and chaparral fuels). In addition, the profiles were remarkably similar across almost all of the fuel types tested. For example, the correlation coefficient r2 of each profile between ponderosa pine (coniferous tree) and manzanita (chaparral) is higher than 0.84. The compositional differences between the two VOC profiles appear to be related to differences in pyrolysis processes of fuel biopolymers at high and low temperatures. These pyrolysis processes are thought to be the main source of VOC emissions. High-temperature and low-temperature pyrolysis processes do not correspond exactly to the commonly used flaming and smoldering categories as described by modified combustion efficiency (MCE). The average atmospheric properties (e.g., OH reactivity, volatility, etc) of the high-and low-temperature profiles are significantly different. We also found that the two VOC profiles can describe previously reported VOC data for laboratory and field burns.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H269O – PubChem

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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 4265-25-2, name is 2-Methylbenzofuran, introducing its new discovery. Product Details of 4265-25-2

(Chemical Equation Presented) Just the one: The combination of palladium dichloride and N,N-dimethylacetamide (DMA) constitutes a highly efficient and reusable catalytic system, which uses molecular oxygen as the sole reoxidant for liquid-phase Wacker oxidation and acetoxylation of terminal olefins to the corresponding methyl ketones and linear allylic acetates, respectively (see scheme). 2006 Wiley-VCH Verlag GmbH Co. KGaA.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H208O – PubChem

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A simple procedure was suggested for the chromatographic analyses of bio-oils from pyrolysis of various feedstock employing different technologies. An acetonitrile solution of each bio-oil was prepared without any extraction or other sample pretreatments. Preliminary thin layer chromatography showed a large number of compounds having a broad range of retention factors (Rfs) among 0-1. Products having a retention factor over 0.9 were mainly detected by GC while some other compounds were only identified by HPLC. GC/MS-FID analysis was used to identify and quantify compounds using peak areas and relative response factors (RRFs). A new equation was proposed to estimate RRFs of compounds identified via their MS spectra when experimental RRFs were not readily available. The novel procedure was employed to characterize bio-oils from pyrolysis of wood of different source or obtained using different pyrolysis procedure. Using this RRF method guaiacol, furfural, butan-2-one, levoglucosan, acetic acid and many other compounds were quantified in bio-oil samples. Different amount of them were found as a function of the type of wood, and pyrolysis conditions adopted. For instance levoglucosan was the main compound using carbon as MW absorber however acetic acid was prevalent when a MW absorber was not employed and both of them were absent in bio-oils from classical heating. The HPLC/MS of bio-oils showed cyclohexancarboxylic acid, 1,2,4-trimethoxybenzene and 2,6-dimethylphenol among the main products present in all bio-oils. On the contrary 4-hydroxyacetophenone and (3,4,5-trimethoxy) acetophenone were present in bio-oil from pyrolysis of wood using MW oven and 2,5-furandiylmethanol when a MW oven without any absorber was employed. Cyclohexanone was present in bio-oils obtained with a thermal heating or a MW oven without any absorber.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H299O – PubChem

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GC×GC-TOFMS was applied to characterize oxygenates in five lignite tars, which were produced from the pyrolysis of a low-maturity lignite in a two-stage reactor with thermal cracking of volatile matter at a different temperature (500?800 C) and without thermal cracking. The analysis of the two tars obtained by no cracking and cracking at 500 C identified 349 and 469 oxygenates with a higher reliability, respectively. Those oxygenates embraced a considerable variety of biomarker species. Many biomarker compounds were the constituents of essential oils or extracts of plants, including long-chain fatty oxygenates (e.g., linolenic acid, erucic acid and 2-hexyldecanol), terpenoids (e.g., cedrenol, caryophyllene oxide and artemisinin) and aromatic compounds (e.g. vanillin, cinnamic acids and flavoniods). Besides, cellulose-degraded primary compounds (e. g., levoglucosenone and furfural) and lignin-derived guaiacols were detected. The results strongly indicated the preservation of various biogenic compositions in the lignite due to the low microbial activity and immature diagenesis. The study also reported the changes of oxygenate classes with cracking temperature by classifying them into chain fatty oxygenates, alicyclic oxygenates and aromatic oxygenates.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H197O – PubChem

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Two fractions of dissolved organic matter (DOM) from a French river, the Gartempe, were obtained using the XAD resin fractionation procedure and were termed hydrophobic acid (HPOA) and transphilic acid (TPIA) according to this method. The composition of these two fractions was investigated with solid state CP/MAS 13C NMR, Curie point pyrolysis at 650C, with and without tetramethylammonium hydroxide (TMAH), and off-line TMAH thermochemolysis at 250C. Separation and identification of the released compounds were performed using gas-chromatography/mass spectrometry (GC/MS). The combination of these techniques allowed determination of the molecular characteristics of each fraction and showed large differences in composition. Solid state CP/MAS 13C NMR revealed a major contribution of lignin-derived units to the hydrophobic acid fraction and the predominance of cellulose in the transphilic acid fraction. Identification of specific molecular structures upon conventional on-line pyrolysis revealed a predominantly lignin type origin for the HPOA fraction and a cellulose one for the TPIA fraction, whereas on-line TMAH/pyrolysis confirmed the presence of acids, phenolic acids and aliphatic diacids, also indicated by solid state CP/MAS 13C NMR in both fractions. Off-line TMAH thermochemolysis was determinant for evidencing the presence of amino acids.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H289O – PubChem

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A dual-zone, continuous feed tubular reactor is developed to assess the potential for formation of products from incomplete combustion in thermal oxidation of common polymers. Solid polymer (cellulose or polystyrene) is fed continuously into a volatilization oven where it fragments and vaporizes. The gas-phase polymer fragments flow directly into a second, main flow reactor to undergo further reaction. Temperatures in the main flow reactor are varied independently to observe conditions needed to convert the initial polymer fragments to CO2 and H2O. Combustion products are monitored at main reactor temperatures from 400 to 850 C and at 2.0-s total residence time with four on-line GC/FIDs; polymer reaction products and intermediates are further identified by GC/MS analysis. Analysis of polymer decomposition fragments at 400 C encompasses complex oxygenated and aromatic hydrocarbon species, which range from high-molecular-weight intermediates of ca. 300 amu, through intermediate mass ranges down to C1 and C2 hydrocarbons, CO, and CO2. Approximately 41 of these species are positively identified for cellulose and 52 for polystyrene. Products from thermal oxidation of cellulose and polystyrene are shown to achieve complete combustion to CO2 and H2O at a main reactor temperature of 850 C under fuel-lean equivalence ratio and 2.0-s reaction time. A dual-zone, continuous feed tubular reactor is developed to assess the potential for formation of products from incomplete combustion in thermal oxidation of common polymers. Solid polymer (cellulose or polystyrene) is fed continuously into a volatilization oven where it fragments and vaporizes. The gas-phase polymer fragments flow directly into a second, main flow reactor to undergo further reaction. Temperatures in the main flow reactor are varied independently to observe conditions needed to convert the initial polymer fragments to CO2 and H2O. Combustion products are monitored at main reactor temperatures from 400 to 850C and at 2.0-s total residence time with four on-line GC/FIDs; polymer reaction products and intermediates are further identified by GC/MS analysis. Analysis of polymer decomposition fragments at 400C encompasses complex oxygenated and aromatic hydrocarbon species, which range from high-molecular-weight intermediates of ca. 300 amu, through intermediate mass ranges down to C1 and C2 hydrocarbons, CO, and CO2. Approximately 41 of these species are positively identified for cellulose and 52 for polystyrene. Products from thermal oxidation of cellulose and polystyrene are shown to achieve complete combustion to CO2 and H2O at a main reactor temperature of 850C under fuel-lean equivalence ratio and 2.0-s reaction time.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H239O – PubChem

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This work evaluates the characteristics of short-term release of volatile and semi-volatile organic chemicals from clothing fabrics that are exposed to environmental tobacco smoke (ETS). Various fabrics were concurrently exposed to ETS in a controlled facility, and the chemicals off-gassed were sampled using solid phase micro-extraction coupled with GC/MS analysis. Toluene-reference concentration (TRC) was calculated for nine selected chemicals and compared.The number of chemicals identified from ETS-exposed fabrics ranged from 13 (polyester and acetate) to 32 (linen). All fabrics off-gassed formaldehyde, tetradecanoic acid and n-hexadecanoic acid, while seven out of eight fabrics emitted furfural, benzonitrile, naphthalene and decanal. Natural fibers of plant origin (cotton and linen) off-gassed higher concentrations (TRC > 100 mug/l) of chemicals that have low molecular weight (?100 or less) than did natural fibers of animal origin (wool and silk) and synthetic fibers. Conversely, wool and silk off-gassed more chemicals that are of high molecular weight (>200), such as TDA (TRC > 100 mug/l) and n-HDA (TRC > 500 mug/l), than did other fabrics. Fabric structure (for a particular material) significantly affects chemical off-gassing. Cotton typically used for polo shirt (knitted) off-gassed significantly (p< 0.05) higher TRC for chemicals with molecular weight of ?100 (such as furfural) than did other cottons of woven style. The dyeing of fabric (white vs. black) had a limited effect on emission, while increasing contact time with ETS increased the intensity of chemical emissions. The mean TRC for cotton exposed for 12. min was nearly doubled than those exposed for 8. min, but no difference existed for polyester. We’ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 4265-25-2, and how the biochemistry of the body works.Synthetic Route of 4265-25-2

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H80O – PubChem

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Benzofuran derivatives and benzofuransare presented as scaffolds in complex molecules and have attracted much attention and prevalent interest due to their interesting biological activity. They also exist in several numbers of naturally occurring compounds and exhibiting biological activity. In this review, we will try to underscore the reactivity of benzofurans through comprehension and giving a full perspective to the readers.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H134O – PubChem

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A benzofuran – 2 – carboxylic acid, which belongs to the benzofuran – 2 – carboxylic acid technical field. Is to metallic iron porphyrin catalytic oxygen oxidation 2 – methyl benzofuran preparation of benzofuran – 2 – carboxylic acid, which belongs to the field of organic synthesis and green chemistry. The method uses 2 – methyl benzofuran as raw materials, in order to ethanol or ethanol aqueous solution as the solvent, metal porphyrin four (O – chlorophenyl) iron porphyrin as catalyst, oxygen as the oxidizing agent, sodium hydroxide or potassium hydroxide is used as the cocatalyst, for 80 – 130 C reaction under 1 – 4 hours, after the reactant is acidified, filtration, recrystallization to obtain product benzofuran – 2 – carboxylic acid. The method of the invention catalyst the amount of raw material weight 0.02 – 0.05%, less catalyst levels and without the need of separation, clean oxygen as the oxidizing agent, and the pressure is 0.5 – 2.0 mpa, solvent environment friendly, the reaction temperature is lower, the reaction raw materials through a simple separation, but also can be recycled. (by machine translation)

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem

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In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 4265-25-2, name is 2-Methylbenzofuran, introducing its new discovery. Computed Properties of C9H8O

A method of purifying a phenol stream that contains a concentration of a contaminating compound is provided. The phenol stream is treated or purified by contacting the stream, under suitable process conditions, with a treatment catalyst that has a low silica content but comprises alumina and a group VIA metal.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H17O – PubChem