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A number of samples from a deep peat bog in Tierra del Fuego were analyzed using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) in order to extract parameters that might be used to interpret the peat chemistry in terms of vegetation change, anaerobic and aerobic decomposition, and fire incidence. The choice of parameters was based on factor analysis of 177 pyrolysis products, quantified for 13 samples, separated into extract and residue, as well as the total samples. Factor analysis of extracts, residues and total samples yielded similar classifications in terms of vegetation and decomposition. Pyrolysis products and ratios that most clearly differentiated samples were used to interpret the depth profile. Although interpretation was not always straightforward, indications of parameters to describe vegetation shifts, aerobic and anaerobic decomposition, and fire largely coincided. These parameters will be used in a forthcoming study for a more complete interpretation of the peat profile.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H265O – PubChem

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There are disclosed compounds of the formula STR1 n is 0-6; A is O or S; B is OR2, SR2 or N(R2)2 ; R1 is hydrogen, loweralkyl, loweralkoxy or halo; R2 is hydrogen or loweralkyl; and the pharmaceutically acceptable salts thereof, and their use in the treatment of leukotriene-mediated naso-bronchial obstructive airpassageway conditions, such as allergic rhinitis, allergic bronchial asthma and the like.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H15O – PubChem

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The aim of this study was to use gas chromatography-mass spectrometry (GC-MS) and APCI-MS techniques to detect adulteration in honey. The key volatile compounds in the headspace of the adulterated honey were marked by GC-MS and their representative fragment ions were utilised in scanning honey samples using the real-time APCI-MS system. The PLS models validated using independent data sets resulted in coefficient of the determination ((Formula presented.)) of 0.97 and 0.96 and root mean square error in prediction (RMSEP) of 2.62 and 2.45 for the GC-MS and APCI-MS data sets respectively. The most efficient volatiles from GC-MS analysis and their corresponding fragment ions m/z from APCI-MS data analysis were then identified and used to develop new PLS models to predict the level of adulteration. The best PLS model gave (Formula presented.) of 0.95 and RMEP of 2.60% in the independent validation set indicating that the model was very accurate in predicting the level of adulteration.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H96O – PubChem

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In many processes proposed for biorefineries, recycling procedures, and industrial or agricultural production processes, residue is generated which could be further transformed by thermochemical conversion via gasification. The technology of dual fluidized bed steam gasification is capable of producing a valuable product gas out of such residue. The generated nitrogen-free product gas can be used for heat and power production and is suitable for separating gases (e.g. hydrogen). However, if the product gas is cleaned, its use as syngas is more beneficial for manufacturing renewable chemical substances, like synthetic natural gas, methanol, Fischer?Tropsch liquids, or mixed alcohols. This paper presents the results of experimental research from gasification test runs of different biogenic fuels, carried out with an advanced 100 kW pilot plant over the last 5 years at TU Wien. The focus is to provide an overview of measured results validated by mass and energy balances and to present key calculated performance indicating key figures of the test runs. In this way, the influence of various operational parameters and the composition of the product gas are evaluated. The presented results form the basis for the proper design of suitable gas-cleaning equipment. Subsequently, the clean syngas is available for several synthesis applications in future biorefineries.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H266O – PubChem

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While the influence of climate, vegetation, management and abiotic site factors on total carbon budgets and turn-over is intensively assessed, the influences of these ecosystem properties on the chemical complexity of soil organic matter (SOM) remains poorly understood. This study addresses the chemical composition of NaOH-extracted SOM from maritime temperate forest sites in Flanders (Belgium) by pyrolysis-GC/MS. The studied forests were chosen based on dominant tree species (Pinus sylvestris, Fagus sylvatica, Quercus robur and Populus spp.), soil texture and soil-moisture conditions. Differences in extractable-SOM pyrolysis products were correlated to site variables including dominant tree species, management of the woody biomass, site history, soil properties, total carbon stocks and indicators for microbial activity. Despite of a typical high intercorrelation between these site variables, the influence of the dominant tree species is prominent. The extractable-SOM composition is strongly correlated to litter quality and available nutrients. In nutrient-poor forests with low litter quality, the decomposition of relatively recalcitrant compounds (i.e. short and mid-chain alkanes/alkenes and aromatic compounds) appears hampered, causing a relative accumulation of these compounds in the soil. However, if substrate quality is favorable, no accumulations of recalcitrant compounds were observed, not even under high soil-moisture conditions. Former heathland vegetation still had a profound influence on extractable-SOM chemistry of young pine forests after a minimum of 60 years.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H304O – PubChem

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Supercritical water gasification of guaiacol as a model compound for lignin was conducted in quartz reactors. The formation and degradation pathways of intermediates were discussed. The results show that the gasification efficiency of guaiacol in supercritical water increased as the reaction time increased. The intermediates in the residual liquid consisted mainly of phenols, arenes, cyclopentanones, alcohols and organic acids. Phenols and arenes were difficult to be gasified in supercritical water and easily turned into char and tar while cyclopentanones, alcohols and organic acids could be easily gasified and turn into hydrogen-rich gas. The Ru/Al2O3 catalyst promoted the degradation of phenols and arenes and thus inhibited the formation of char and tar.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H357O – PubChem

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A facile sulfenylation of various aromatic nuclei was achieved by use of the novel sulfenylation reagent, the quinone mono O,S-acetal bearing a pentafluorophenylthio group. It functioned below 0C in the presence of a catalytic amount of TMSOTf.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H201O – PubChem

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A new strategy for the synthesis of 2-Methylbenzofurans via the intramolecular Heck reaction has been developed. This efficient palladium-catalyzed system showed good catalytic activity. Various substituted 2-methylbenzofurans could be afforded in good to excellent yields.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H356O – PubChem

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In the right light: UV light triggers bond breaking, liberates a caged carboxylic acid, and generates the central C=C double bond in the photoresponsive hexatriene molecule of a dithienylethene molecular switch. Light of the same wavelength converts the colorless isomer into its colored counterpart (see picture) in a visually convenient method to report on the success of the release event. Copyright

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H323O – PubChem

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To reveal the structural factors associated with free radicals in humic substances (HSs) with lower degrees of humification that are comparable to Type Rp, correlations between free radical content and chemical properties of 10 humic acids (HAs) and 2 fulvic acids (FAs) from different sources were investigated. Free radical contents of the HSs were analyzed using electron spin resonance spectroscopy (ESR) and ranged from 7.0 × 1015-5.7 × 1017spins g-1 carbon. The relative abundances for aromatic and/or olefin, alkyl, and carboxylic carbon species in the HSs were determined using solid state cross polarization magic angle spinning (CPMAS) 13C nuclear magnetic resonance spectroscopy (NMR). Aromaticity of the HSs estimated from 13C NMR varied slightly (30-40%) and no correlation was observed between aromaticity and free radical content. In contrast, a positive exponential relationship was observed between relative abundance of carboxyl groups and free radical content in HAs, while a negative exponential relationship was observed between relative abundance of alkyl carbon and free radical content. Two FAs were outliers in the correlations, probably due to the different chemical properties between HAs and FAs. Analysis of structural fragments using pyrolysis-gas chromatography-mass spectrometry (GC/MS) showed that additional chemical properties were also positively correlated with free radical content in HAs: two or more acidic functional groups-substituted phenolic compounds, short chain dicarboxylic acids, hydroxyacetic acid, nitrogen-containing compounds and heterocyclic carbonyl compounds. Possible semiquinone precursors, such as methoxyphenols, were not related to free radical content. These results show that free radicals are stabilized by combinations of multiple polar components such as carboxyl and nitrogen-containing carbons within HA structures during the early stages of humification.

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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H330O – PubChem