Liu, Yu; Taylor, Laurence J.; Argent, Stephen P.; McMaster, Jonathan; Kays, Deborah L. published the article 《Group 11 m-Terphenyl Complexes Featuring Metallophilic Interactions》. Keywords: gold silver copper terphenyl complex preparation metallophilic interaction; crystal structure mol gold silver copper terphenyl complex optimized.They researched the compound: Silver(I) trifluoromethanesulfonate( cas:2923-28-6 ).Safety of Silver(I) trifluoromethanesulfonate. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:2923-28-6) here.
A series of group 11 m-terphenyl complexes have been synthesized via a metathesis reaction from the Fe(II) complexes (2,6-Mes2C6H3)2Fe and (2,6-Xyl2C6H3)2Fe (Mes = 2,4,6-Me3C6H2; Xyl = 2,6-Me2C6H3). [2,6-Mes2C6H3M]2 (1 M = Cu; 2 M = Ag; 6 M = Au) and [2,6-Xyl2C6H3M]2 (3 M = Cu; 4 M = Ag) are dimeric in the solid state, although different geometries are observed depending on the ligand. These complexes feature short metal-metal distances in the expected range for metallophilic interactions. While 1-4 are readily isolated using this metathetical route, the Au complex 6 is unstable in solution at ambient temperatures and has only been obtained in low yield from the decomposition of (2,6-Mes2C6H3)Au·SMe2 (5). NMR spectroscopic measurements, including Diffusion Ordered Spectroscopy (DOSY), suggest 1-4 remain dimeric in benzene-d6 solution The metal-metal interactions have been examined computationally using the Quantum Theory of Atoms in Mols. (QTAIM) and by an energy decomposition anal. employing naturalized orbitals for chem. valence (EDA-NOCV).
In some applications, this compound(2923-28-6)Safety of Silver(I) trifluoromethanesulfonate is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem