《Generation and Reactivity of a NiIII2(μ-1,2-peroxo) Complex》 was written by Zhao, Norman; Filatov, Alexander S.; Xie, Jiaze; Hill, Ethan A.; Rogachev, Andrey Yu.; Anderson, John S.. HPLC of Formula: 5471-63-6 And the article was included in Journal of the American Chemical Society in 2020. The article conveys some information:
High-valent transition metal-oxo, -peroxo, and -superoxo complexes are crucial intermediates in both biol. and synthetic oxidation of organic substrates, water oxidation, and oxygen reduction While high-valent oxygenated complexes of Mn, Fe, Co, and Cu are increasingly known, high-valent oxygenated Ni complexes are comparatively rarer. Herein authors report the isolation of such an unusual high-valent species in a thermally unstable NiIII2(μ-1,2-peroxo) complex, which was characterized using single-crystal x-ray diffraction and x-ray absorption, NMR, and UV-visible spectroscopies. Reactivity studies show that this complex is stable toward dissociation of oxygen but reacts with simple nucleophiles and electrophiles.1,3-Diphenylisobenzofuran(cas: 5471-63-6HPLC of Formula: 5471-63-6) was used in this study.
1,3-Diphenylisobenzofuran(cas: 5471-63-6) can be used as a fluorescent probe for detection of superoxide anion radical (O2−) inside the membrane lipid layer by DPBF fluorescence quenching method. 1,3-Diphenylisobenzofuran(DPBF) can be used as quencher during the photoinactivation of TA-3 mouse mammary carcinoma cells containing hematoporphyrin.HPLC of Formula: 5471-63-6
Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem