Snegaroff, Katia’s team published research in Chemistry – A European Journal in 16 | CAS: 69626-75-1

Chemistry – A European Journal published new progress about 69626-75-1. 69626-75-1 belongs to benzofurans, auxiliary class Iodide,Benzofuran, name is 2-Iodobenzofuran, and the molecular formula is C7H13NO2, Formula: C8H5IO.

Snegaroff, Katia published the artcileDeprotonative Metalation of Substituted Benzenes and Heteroaromatics Using Amino/Alkyl Mixed Lithium-Zinc Combinations, Formula: C8H5IO, the publication is Chemistry – A European Journal (2010), 16(27), 8191-8201, S8191/1-S8191/50, database is CAplus and MEDLINE.

Various homoleptic and heteroleptic lithium-zinc combinations were prepared, and structural elements obtained on the basis of NMR spectroscopic experiments and DFT calculations In light of their ability to metalate anisole, pathways were proposed to justify the synergy observed for some mixtures The best basic mixtures were obtained either by combining ZnCl2·TMEDA (TMEDA = N,N,N’,N’-tetramethylethylenediamine) with [Li(tmp)] (tmp = 2,2,6,6-tetramethylpiperidine; 3 equiv) or by replacing one of the tmp in the precedent mixture with an alkyl group. The reactivity of the aromatic lithium zincates supposedly formed was next studied, and proved to be substrate-, base-, and electrophile-dependent. The aromatic lithium zincates were finally involved in palladium-catalyzed cross-coupling reactions with aromatic chlorides and bromides.

Chemistry – A European Journal published new progress about 69626-75-1. 69626-75-1 belongs to benzofurans, auxiliary class Iodide,Benzofuran, name is 2-Iodobenzofuran, and the molecular formula is C7H13NO2, Formula: C8H5IO.

Referemce:
https://en.wikipedia.org/wiki/Benzofuran,
Benzofuran | C8H6O – PubChem