Related Products of 2923-28-6. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Photoswitchable fluorescent self-assembled metallacycles with high photostability. Author is Chen, Shangjun; Chen, Lijun; Cai, Yunsong; Zhu, Wei-Hong.
In this study, photoswitchable fluorescent supramol. metallacycles with high fatigue-resistance have been constructed by coordination-driven self-assembly by using bithienylethene with dipyridyl units (BTE) as a coordination donor and a fluorescent di-platinum(II) (Pt-F) as a coordination acceptor. The photo-triggered reversible transformation between the ring-open and ring-closed form of the metallacycles was confirmed by 1H NMR, 31P NMR, and UV/Vis spectroscopy. This unique property enabled a reversible noninvasive “”off-on”” switching of fluorescence through efficient Foerster resonance energy transfer (FRET). Importantly, the metallacycles remained structurally intact after up to 10 photoswitching cycles. The photoresponsive property and exceptional photostability of the metallacycles posit their potential promising application in optical switching, image storage, and super-resolution microscopy.
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Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem