Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Sylvain, C, once mentioned the application of 98760-08-8, Name is (2R,3S)-1,2-Epoxy-3-(Boc-amino)-4-phenylbutane, molecular formula is C15H21NO3, molecular weight is 263.3321, MDL number is MFCD00671705, category is dioxoles. Now introduce a scientific discovery about this category, Product Details of 98760-08-8.
Reinvestigation of birch reduction of benzo[1,3]dioxoles and further transformations of the resulting dihydro compounds
In spite of early reports by Birch, we demonstrated that treatment of benzodioxoles with sodium in ammonia in the presence of methanol almost quantitatively yields the corresponding dihydro compounds. Despite their poor stability these compounds are synthetically useful. Treatment of 5-isobutyl-4,7-dihydrobenzo[1,3]dioxole with bromotrimethylsilane gives 6-hydroxy-3-isobutylcyclohex-2-enone in 80% yield. Treatment of 4,7-dihydrobenzo[1,3]dioxole with potassium in liquid ammonia in the presence of iron(III) chloride leads to 3a,4-dihydrobenzo[1,3]dioxole in high yield..
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem