Ndungu, J. Maina’s team published research in Organic Letters in 7 | CAS: 69626-75-1

Organic Letters published new progress about 69626-75-1. 69626-75-1 belongs to benzofurans, auxiliary class Iodide,Benzofuran, name is 2-Iodobenzofuran, and the molecular formula is C8H5IO, COA of Formula: C8H5IO.

Ndungu, J. Maina published the artcileDevelopment of an Anomalous Heck Reaction: Skeletal Rearrangement of Divinyl and Enyne Carbinols, COA of Formula: C8H5IO, the publication is Organic Letters (2005), 7(26), 5845-5848, database is CAplus and MEDLINE.

A general set of conditions that achieves the union of aryl halides and divinyl or enyne carbinols to afford tri- or tetrasubstituted olefins in good yields (up to 83%) is described. E.g., reaction of BrPh and CH2:CHCH(OH)CMe:CH2 in presence of PdCl2(PPh3)2, i-Pr2NEt, and Et4NCl gave olefin I. The mechanism by which this proceeds is believed to involve the intermediacy of a cyclopropanol, followed by a novel skeletal reorganization. The ability to suppress β-hydride elimination of organopalladium intermediates appears to be critical to the success of these processes.

Organic Letters published new progress about 69626-75-1. 69626-75-1 belongs to benzofurans, auxiliary class Iodide,Benzofuran, name is 2-Iodobenzofuran, and the molecular formula is C8H5IO, COA of Formula: C8H5IO.

Referemce:
https://en.wikipedia.org/wiki/Benzofuran,
Benzofuran | C8H6O – PubChem