Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 51166-71-3, Name is 2,6-Di-O-methyl-¦Â-cyclodextrin, SMILES is COC[C@@H]1[C@]2([H])[C@@H]([C@@H](OC)[C@](O[C@]3([H])[C@H](O[C@@](O[C@]4([H])[C@H](O[C@@](O[C@]5([H])[C@H](O[C@@](O[C@@]6([H])[C@H](O)[C@@H](OC)[C@@](O[C@@H]6COC)([H])O[C@@]7([H])[C@H](O)[C@@H](OC)[C@@](O[C@@H]7COC)([H])O[C@@]8([H])[C@H](O)[C@@H](OC)[C@@](O[C@@H]8COC)([H])O2)([H])[C@H](OC)[C@H]5O)COC)([H])[C@H](OC)[C@H]4O)COC)([H])[C@H](OC)[C@H]3O)COC)([H])O1)O, in an article , author is HUNG, MH, once mentioned of 51166-71-3, Application In Synthesis of 2,6-Di-O-methyl-¦Â-cyclodextrin.
THERMAL-DECOMPOSITION OF FLUORINATED DIOXOLANE CARBOXYLATES
Synthesis of fluorodioxole olefin monomers by thermal decomposition of fluorinated dioxolane carboxylic acid and the corresponding acyl chloride was explored. Complex product formation is observed, including acyl fluoride from Cl-F exchange, the hydro-dioxolane from proton abstraction, the cyclic ether ketone from dioxolane ring opening, and the epoxy acid fluoride from thermal rearrangement. The product distribution is strongly dependent upon reaction conditions. The main influential factors include the reaction temperature, the base used for the reaction, the presence or absence of solvent, and the counter ion associated with the intermediate salt. A mechanism is proposed to rationalize both the results and the product distribution. Methods to make authentic samples for product analysis are reported.
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem