Category: 57319-65-0

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Herein, we show that mesoporous titania-supported gold nanoparticle assemblies (Au/MTA) catalyze the activation of NaBH4 and 1,1,3,3-tetramethyl disiloxane (TMDS) compounds, which act as transfer hydrogenation agents for the reduction of nitroarenes to the corresponding anilines in moderate to high yields. On the other hand, nitroalkanes are reduced to the corresponding diazo and hydrazo compounds under the studied conditions. The substantial measured primary kinetic isotope effects found here suggested that B-H bond cleavage occurs in a rate-determining step and [Au]-H active hybrids are formed, which are responsible for the reduction of nitroarenes to the corresponding amines. Formal Hammett-type kinetic analysis of a range of para-X-substituted nitroarenes lends support to this hypothesis. Nitro compounds substituted with electron-withdrawing groups were reduced faster than the corresponding compounds with electron-donating groups. The presence of water enhanced the catalytic activity of Au/MTA in aprotic solvents. Nuclear magnetic resonance studies support the formation of the corresponding hydroxylamines as the only intermediate products. On the basis of the high observed chemoselectivities and the fast and clean reaction processes, these catalytic systems, i.e., Au/MTA-NaBH4 and Au/MTA-TMDS, show promise for the efficient synthesis of aromatic amines at industrial levels.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H1387O – PubChem

In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Formula: C8H7NO2, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 57319-65-0, name is 6-Aminoisobenzofuran-1(3H)-one. In an article，Which mentioned a new discovery about 57319-65-0

A novel strategy for aromatic trifluoromethylation by converting amino into trifluoromethyl groups via a Sandmeyer-type reaction is reported. The transformation involves diazotization of the aromatic amines with tert-butyl nitrite and hydrochloric acid to form aryldiazonium chlorides, followed by trifluoromethylation with trifluoromethylsilver at low temperature. Various readily available aromatic amines are smoothly converted under mild conditions. Georg Thieme Verlag Stuttgart. New York.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H1417O – PubChem

One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Safety of 6-Aminoisobenzofuran-1(3H)-one, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 57319-65-0, Name is 6-Aminoisobenzofuran-1(3H)-one, molecular formula is C8H7NO2

A one-pot synthesis of chiral C(3)-substituted phthalides via an indium-mediated allylation/transesterification reaction is described. The development of this reaction was facilitated through the applied use of DFT calculations to rationalize the stereoselection of a chiral In-mediated process. It was discovered that the enantiomeric excess of this reaction depended upon the steric size, chain length, and substitution of the aldehyde employed.

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Related Products of 57319-65-0, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.57319-65-0, Name is 6-Aminoisobenzofuran-1(3H)-one, molecular formula is C8H7NO2. In a Patent，once mentioned of 57319-65-0

Disclosed are compounds having Formula (I) and the compositions and methods relating to these compounds, for treating or preventing a viral infection mediated at least in part by a virus in the Flaviviridae family of viruses, wherein A, R2, m, R, V, W, T, Z, R1, Y, and p are disclosed herein.

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Benzofuran – Wikipedia,
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A novel strategy for aromatic trifluoromethylation by converting aromatic amino group into CF3 group is reported herein. This method, which can be considered as trifluoromethylation variation of the classic Sandmeyer reaction, uses readily available aromatic amines as starting materials and is performed under mild conditions.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H1416O – PubChem

In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Computed Properties of C8H7NO2, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 57319-65-0, name is 6-Aminoisobenzofuran-1(3H)-one. In an article，Which mentioned a new discovery about 57319-65-0

Compounds of the present invention and pharmaceutically acceptable compositions thereof, are useful as modulators of ATP-Binding Cassette (?ABC?) transporters or fragments thereof, including Cystic Fibrosis Transmembrane Conductance Regulator (?CFTR?). The present invention also relates to methods of treating ABC transporter mediated diseases using compounds of the present invention.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H1367O – PubChem

Synthetic Route of 57319-65-0, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.57319-65-0, Name is 6-Aminoisobenzofuran-1(3H)-one, molecular formula is C8H7NO2. In a article，once mentioned of 57319-65-0

We have demonstrated that a combination of indium(III) iodide and 1,1,3,3-tetramethyldisiloxane (TMDS) effectively catalyzes the chemoselective reduction of nitrobenzenes with a variety of functional groups (halogens, alkyl, alkoxy, hydroxy, ester, amino, amide, cyanide, thiol, and an alkene moiety), producing the corresponding aniline derivatives.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H1411O – PubChem

One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Product Details of 57319-65-0, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 57319-65-0, Name is 6-Aminoisobenzofuran-1(3H)-one, molecular formula is C8H7NO2

Enediyne compounds having a structure according to formula (I), where R0, R2, R3, R4, R5, R6, and R7 are defined herein, can be used in chemotherapeutic drugs, especially in conjugates, for the treatment of diseases such as cancer.

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Benzofuran – Wikipedia,
Benzofuran | C8H1361O – PubChem

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In one aspect, the present disclosure provides new analogs of uncialamycin of formulae (I) and (II). The present disclosure also provides novel synthetic pathways to obtaining uncialamycin and analogs thereof. Additionally, the present disclosure also describes methods of use of uncialamycin and analogs thereof. In another aspect, the present disclosure provides antibody-drug conjugates comprising the compounds of formulae (I) and (ll).

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Benzofuran – Wikipedia,
Benzofuran | C8H1365O – PubChem

In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Application In Synthesis of 6-Aminoisobenzofuran-1(3H)-one, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 57319-65-0, name is 6-Aminoisobenzofuran-1(3H)-one. In an article，Which mentioned a new discovery about 57319-65-0

The 13C and 1H NMR spectra of several phthalides, phthalimides, phthalimidines and 1-hydroxyphthalimidines, many of them bearing an amino substituent at the aromatic ring, have been recorded and analysed.Chemical shifts were correlated by multiple linear regression analysis and substituent shift parameters were calculated.In most cases, standard deviations were lower than 0.5 ppm for 13C and 0.05 ppm for 1H spectra.Agreement between calculated and experimental shifts was satisfactory and permitted unequivocal structure assignment.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H1378O – PubChem