In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Terpyridine based ReX(CO)3 compounds (X = Br-, N-3 and triazolate): Spectroscopic and DFT studies, published in 2021-01-15, which mentions a compound: 2923-28-6, mainly applied to preparation rhenium phenylmorpholineterpyridine carbonyl bromide azide complex; crystal mol structure rhenium phenylmorpholineterpyridine carbonyl bromide azide complex; antimicrobial activity rhenium phenylmorpholineterpyridine carbonyl bromide azide complex; protein affinity rhenium phenylmorpholineterpyridine carbonyl bromide azide complex, Formula: CAgF3O3S.
[ReX(CO)3(L-k2N1,N2)] (L = 4′-(4-Ph morpholine)-2,2′:6′,2”-terpyridine, X = Br- (1), N3- (2), and triazolate (3)) complexes were synthesized, and characterized using different spectroscopic and anal. tools including single-crystal X-ray diffraction anal. of 2. The 1,3-dipolar cycloaddition reaction between 2, and 4,4,4-trifluoro-2-butynoic acid Et ester afforded triazolate 3. Although, the crystal structure of 2 showed that the azide ligand is terminally coordinated to Re(CO)+3 unit, the 19F and 1H NMR analyses of 3 provided conversant evidences that the kinetically formed N(1) triazolate bound isomer favored the isomerization to N(2) form. The photophys. properties of 1-3 were studied by recording the absorption spectra of the compounds in solvents of different polarities. Complexes 1 and 3 were screened for their potential antimicrobial activities. The protein binding affinity of 1, and 3 towards hen white egg lysozyme revealed that the bromide complex exchanges Br- with that protein, while the triazolate analog sticked around.
This literature about this compound(2923-28-6)Formula: CAgF3O3Shas given us a lot of inspiration, and I hope that the research on this compound(Silver(I) trifluoromethanesulfonate) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem