Synthetic Route of 97148-39-5, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, 97148-39-5, Name is Ammonium (Z)-2-(furan-2-yl)-2-(methoxyimino)acetate, SMILES is O=C([O-])/C(C1=CC=CO1)=NOC.[NH4+], belongs to benzofurans compound. In a article, author is Dasgupta, Ayan, introduce new discover of the category.
Borane-Catalyzed Stereoselective C-H Insertion, Cyclopropanation, and Ring-Opening Reactions
Lewis acidic boranes have been shown to be effective metal-free catalysts for highly selective reactions of donor-acceptor diazo compounds to a range of substrates. The reactions of alpha-aryl alpha-diazoesters with nitrogen heterocycles indole or pyrrole selectively generate C3 and C2 C-H insertion products, respectively, in good to excellent yields even when using unprotected indoles. Alternatively, benzofuran, indene, and alkene substrates give exclusively cyclopropanated products with alpha-aryl alpha-diazoesters, whereas the reactions with furans lead to ring-opening. Comprehensive theoretical calculations have been used to explain the differing reactivities and high selectivities of these reactions. Overall, this work demonstrates the selective metal-free catalytic reactions of alpha-aryl alpha-diazoesters with (hetero)cycles and alkenes. This simple, mild reaction protocol represents an alternative to the commonly used precious metal systems and may provide future applications in the generation of biologically active compounds.
Synthetic Route of 97148-39-5, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 97148-39-5.
Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem