The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about Synthesis and study of Re(I) tricarbonyl complexes based on octachloro-1,10-phenanthroline: Towards deep red-to-NIR emitters, the main research direction is rhenium chlorophenanthroline preparation red NIR luminescence; crystal structure rhenium perchlorophenanthroline carbonyl.Computed Properties of CAgF3O3S.
To shift the emission of classical [Re(CO)3(NN̂)X]0/+ complexes to the NIR region, the authors proposed a novel and efficient design strategy based on perchlorination of the diimine (NN̂) ligands. In pursuing this goal, the authors have exploited octachloro-1,10-phenanthroline (phen-Cl8), a strong π-acceptor ligand, to synthesize complexes of [Re(phen-Cl8)(CO)3Br], [Re(phen-Cl8)(CO)3OTf], and [Re(phen-Cl8)(CO)3(MeCN)]OTf type. The emission of these compounds in solid and solution states is significantly red shifted by 131-186 nm compared to their parent H-analogs. The perchloronation effect most pronouncedly appears for [Re(phen-Cl8)(CO)3Br], whose emission maxima are 685 and 730 nm in solid and solution states, i.e. red shifted by 186 nm (0.539 eV) and 158 nm (0.543 eV), resp., relative to [Re(phen)(CO)3Br]. The in-depth spectral and DFT studies indicate that the above complexes emit phosphorescence of 3(M + X)LCT character (X = CO + Lan).
After consulting a lot of data, we found that this compound(2923-28-6)Computed Properties of CAgF3O3S can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem