Electric Literature of 591-11-7, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 591-11-7, Name is 5-Methylfuran-2(5H)-one, SMILES is O=C1OC(C)C=C1, belongs to benzofurans compound. In a article, author is Mando, Morgane, introduce new discover of the category.
Organocatalytic enantioselective allylic alkylation of alpha-aryl gamma-lactones: an approach to densely functionalized quaternary stereocentres
The asymmetric allylic alkylation (AAA) of alpha-aryl gamma-lactones involving the activation of Morita-Baylis-Hillman (MBH) carbonates by an original chiral Lewis base is reported. A wide range of gamma-lactones bearing a quaternary stereocentre was thus obtained in both high yields and high enantiomeric ratios. The direct alkylation by MBH alcohol usingin situactivation has been also established. Additionally synthetically useful functional transformations of groups surrounding the quaternary stereocentre have been performed.
Electric Literature of 591-11-7, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 591-11-7 is helpful to your research.
Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem