On September 16, 2022, Chen, Doris; Jones, Elizabeth V.; Williams, Corey W.; Huynh, Tan-Khang N.; McPhail, Tristan C.; France, Stefan published an article.Recommanded Product: 5-Iodobenzofuran The title of the article was Intramolecular, Interrupted Homo-Nazarov Cascade Biscyclizations to Angular (Hetero)Aryl-Fused Polycycles. And the article contained the following:
A SnCl4-catalyzed intramol., interrupted homo-Nazarov cascade biscyclization to access angular (hetero)aryl-fused polycycles was reported. Subsequent decarboxylation of the readily enolizable products afforded the angular products in up to 71% yield over two steps, with the trans-diastereomers as the major products. The cyclopropyl homo-Nazarov cyclization precursors were formed using a scalable and modular synthetic route that, ultimately, offers access to 6,6,6-, 6,6,5-, 6,5,6-, 6,6,5,6-, and 6,6,6,5-fused angular polycyclic products. To showcase the rigor and utility of the method, an 8-step total synthesis of (±)-1-oxoferruginol, an antibacterial aromatic abietane diterpenoid, was disclosed. The experimental process involved the reaction of 5-Iodobenzofuran(cas: 60770-67-4).Recommanded Product: 5-Iodobenzofuran
The Article related to alkenyl cyclopropyl ketone tin chloride homo nazarov biscyclization decarboxylation, angular polycyclic compound preparation diastereoselective, cation-pi cyclizations, domino reactions, donor-acceptor cyclopropanes, oxyallyl cations, ring-opening cyclizations and other aspects.Recommanded Product: 5-Iodobenzofuran
Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem