Chemical Properties and Facts of 767291-67-8

Different reactions of this compound((1S,2S)-N1,N2-Bis(3,3-dimethylbutyl)-N1,N2-dimethylcyclohexane-1,2-diamine)Synthetic Route of C20H42N2 require different conditions, so the reaction conditions are very important.

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Canipa, Steven J.; Stute, Annika; O’Brien, Peter researched the compound: (1S,2S)-N1,N2-Bis(3,3-dimethylbutyl)-N1,N2-dimethylcyclohexane-1,2-diamine( cas:767291-67-8 ).Synthetic Route of C20H42N2.They published the article 《Use of copper(II)/diamine catalysts in the desymmetrization of meso-diols and asymmetric Henry reactions: comparison of (-)-sparteine and (+)-sparteine surrogates》 about this compound( cas:767291-67-8 ) in Tetrahedron. Keywords: acylation benzoylation Henry reaction catalyst copper diamine sparteine. We’ll tell you more about this compound (cas:767291-67-8).

Four new copper(II)/diamine complexes comprising some (+)-sparteine surrogates and a cyclohexane-derived diamine were prepared and evaluated as chiral catalysts in desymmetrization of meso-diols and an asym. Henry reaction. A mono-benzoylation reaction generated two products with high enantioselectivity (90:10 to 97:3 er). An asym. Henry reaction gave nitro alcs. in 90:10 to 98:2 enantiomeric ratio (er). Notably, the sense of induction with the (+)-sparteine surrogates was opposite to that obtained using the copper(II)/(-)-sparteine complex. One of the nitro alc. products was used in a concise synthesis of a chiral morpholine derivative, (2S)-2-phenylmorpholine. Under optimized conditions the synthesis of the target compounds was achieved using (1R,2S)-rel-1,2-diphenyl-1,2-ethanediol and benzoyl chloride as starting materials and (7S,7aR,14S,14aS)-dodecahydro-7,14-methano-2H,6H-dipyrido[1,2-a:1′,2′-e][1,5]diazocine-copper complex [(-)-sparteine-copper complex] as catalyst. The title compound thus formed was (1S,2R)-1,2-diphenyl-1,2-ethanediol 1-benzoate. Using a sparteine surrogate, such as (+)-(1R,5S,11aS)-Decahydro-3-methyl-1,5-methano-2H-pyrido[1,2-a][1,5]diazocine-copper complex gave (1R,2S)-1,2-diphenyl-1,2-ethanediol 1-benzoate.

Different reactions of this compound((1S,2S)-N1,N2-Bis(3,3-dimethylbutyl)-N1,N2-dimethylcyclohexane-1,2-diamine)Synthetic Route of C20H42N2 require different conditions, so the reaction conditions are very important.

Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem