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A novel heteroacene, 2-(2,3,4,5-tetrafluorophenyl)-1H-imidazo[4,5-b] phenazine has been successfully synthesized. The heteroacene can selectively detect F- over Cl-, Br-, I-, NO 3-, HSO4-, ClO4 -, and BF4- in organic solvents through colorimetric and fluorescent responses. The interaction between the heteroacene and F- was investigated through UV-Vis, fluorescence, and 1H NMR titration experiments, which suggested that the effects might occur via a combined process including hydrogen bond, deprotonation, and anion-pi interactions between the sensor and F-.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H3777O – PubChem