The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Silver(I) trifluoromethanesulfonate, is researched, Molecular CAgF3O3S, CAS is 2923-28-6, about An Air-Stable Alkene-Derived Organic Radical Cation, the main research direction is air stable alkene derived organic radical cation.Safety of Silver(I) trifluoromethanesulfonate.
Alkenes are known to undergo oxidation to radical cations and dications. The radical cations are often highly reactive and not stable under air. Herein, the authors report the synthesis, isolation, characterization, and mol. structure of an alkene-derived radical cation A, which is stable in air both in the solid state and in solution The access to this compound was facilitated from E-diamino tri-substituted alkene B as a synthon for the synthesis of A through one-electron oxidation The E-diamino tri-substituted alkene B was synthesized by the two-electron reduction of N,N’-1,2-propylene-bridged bis-2-phenyl-pyrrolinium cation C. Under two-electron oxidation, alkene B transforms back to cation C involving a double carbocation rearrangement.
《An Air-Stable Alkene-Derived Organic Radical Cation》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Silver(I) trifluoromethanesulfonate)Safety of Silver(I) trifluoromethanesulfonate.
Reference:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem