Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 6296-53-3, Name is N-(1,3-Dioxo-1,3-dihydroisobenzofuran-4-yl)acetamide, molecular formula is C10H7NO4. In an article, author is Sekino, Katsutoshi,once mentioned of 6296-53-3, Quality Control of N-(1,3-Dioxo-1,3-dihydroisobenzofuran-4-yl)acetamide.
Fluoride-Ion-Catalyzed Synthesis of Ladder-type Conjugated Benzobisbenzofurans via Intramolecular Nucleophilic Aromatic Substitution Reaction under Metal-free and Mild Conditions
The fluoride-ion-catalyzed synthesis of benzobis-benzofuran derivatives is described. Fluorine-containing aryl silyl ethers were reacted with 5 mol % of Bu4NF to give desired compounds in high yield under mild conditions. Syn-selective cyclization reaction was discovered for a particular compound as a kinetic product. Computational analysis revealed that the fluorine substituents in the anti-type benzobisbenzofurans affect the order of the molecular orbitals.
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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem