Reference of 4687-25-6, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 4687-25-6, Benzofuran-3-carbaldehyde, introducing its new discovery.
Palladium-catalyzed asymmetric benzylation of 3-aryl oxindoles
Herein we report palladium-catalyzed asymmetric benzylic alkylation with 3-aryl oxindoles as prochiral nucleophiles. Proceeding analogously to asymmetric allylic alkylation, asymmetric benzylation occurs in high yield and enantioselectivity for a variety of unprotected 3-aryl oxindoles and benzylic methyl carbonates using chiral bisphosphine ligands. This methodology represents a novel asymmetric carbon-carbon bond formation between a benzyl group and a prochiral nucleophile to generate a quaternary center.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 4687-25-6. In my other articles, you can also check out more blogs about 4687-25-6
Reference£º
Benzofuran – Wikipedia,
Benzofuran | C8H1216O – PubChem