Recently I am researching about RADICAL REACTIONS; INTERMEDIATE; PHOTOLYSIS; CHEMISTRY, Saw an article supported by the Hellenic Foundation for Research and Innovation (HFRI); General Secretariat for Research and Technology (GSRT), under the HFRI PhD Fellowship grant [4813]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Tzirakis, MD; Malliaros, NG; Orfanopoulos, M. The CAS is 87-41-2. Through research, I have a further understanding and discovery of Isobenzofuran-1(3H)-one. Safety of Isobenzofuran-1(3H)-one
A new, simple, and rapid photochemical reaction of o-phthalaldehyde with C-60 has been disclosed. This reaction afforded exclusively the unanticipated C-60-phthalide derivative 11 in good yield. The formation of this product is consistent with the intervention of a key free-radical intermediate -a benzylic radical- in the course of the reaction. The structure of 11 has been determined by the combined use of experimental and theoretical NMR studies. In the course of this study we further disclosed a new mode of radical reactivity of C-60 with a series of substituted phthalides (2, 15-17) catalyzed by tetrabutylammonium decatungstate.
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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem