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Oviposition Stimulants for the Lesser Mulberry Pyralid, Glyphodes pyloalis (WALKER), in Mulberry Leaves; Rediscovery of Phytoalexin Components as Insect Kairomones
The oviposition stimulant for the lesser mulberry pyralid, Glyphodes pyloalis WALKER, was isolated from an acetone extract of mulberry (Morus alba L.) leaves, and its structure was identified as 2-(3′,5′-dihydroxy-4′-prenylphenyl)-6-hydroxybenzofuran, viz. moracin C (1), a known phytoalexin from fungus-infected mulberry shoot.Moracin N (2) and omega-hydroxy moracin N (3) were also identified in the extract, but no ovipositional activity was demonstrated in these compounds.Synthetic moracin M, 2-(3′,5′-dihydroxyphenyl)-6-hydroxybenzofuran (4), as the basic skeleton of moracins, indicated weak activity as an oviposition stimulant.The increase in susceptibility of already-infested mulberry leaf is discussed in relation to the production of phytoalexins.All these compounds except omega-hydroxy moracin N (3) are known as phytoalexins in the mulberry tree.
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Benzofuran – Wikipedia,
Benzofuran | C8H419O – PubChem