Simple exploration of 6-Methylisobenzofuran-1(3H)-one

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A new catalyst system capable of selective chloride functionalization in the Pd-catalyzed amination of 3,2- and 5,2- Br/Cl-pyridines is reported. A reaction optimization strategy employing ligand parametrization led to the identification of 1,1?-bis[bis(dimethylamino)phosphino]ferrocene “DMAPF”, a readily available yet previously unutilized diphosphine, as a uniquely effective ligand for this transformation.

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Reference：
Benzofuran – Wikipedia,
Benzofuran | C8H1348O – PubChem