Product Details of 87-41-2. Qian, SQ; Li, ZQ; Li, MY; Wisniewski, SR; Qiao, JX; Richter, JM; Ewing, WR; Eastgate, MD; Chen, JS; Yu, JQ in [Qian, Shaoqun; Li, Zi-Qi; Li, Minyan; Yu, Jin-Quan] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA; [Wisniewski, Steven R.; Eastgate, Martin D.] Bristol Myers Squibb, Chem & Synthet Dev, New Brunswick, NJ 08903 USA; [Chen, Jason S.] Scripps Res Inst, Automated Synth Facil, La Jolla, CA 92037 USA; [Qiao, Jennifer Xiaoxin; Ewing, William R.] Bristol Myers Squibb, Discovery Chem, Princeton, NJ 08543 USA; [Richter, Jeremy M.] Bristol Myers Squibb, Res & Dev, Hopewell, NJ 08534 USA published Ligand-Enabled Pd(II)-Catalyzed C(sp(3))-H Lactonization Using Molecular Oxygen as Oxidant in 2020, Cited 41. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2.
Pd(II)-catalyzed C-H lactonization of o-methyl benzoic acid substrates has been achieved using molecular oxygen as the oxidant. This finding provides a rare example of C-H oxygenation through Pd(II)/Pd(0) catalysis as well as a method to construct biologically important benzolactone scaffolds. The use of a gas mixture of 5% oxygen in nitrogen demonstrated the possibility for its application in pharmaceutical manufacturing.
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Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem