Application of 5471-63-6In 2020 ,《Steric effects on deprotonative generation of cyclohexynes and 1,2-cyclohexadienes from cyclohexenyl triflates by magnesium amides》 was published in Tetrahedron. The article was written by Hioki, Yuto; Mori, Atsunori; Okano, Kentaro. The article contains the following contents:
Steric effects on the deprotonative generation of cyclohexynes and 1,2-cyclohexadienes from cyclohexenyl triflates are described. A cyclohexenyl triflate, which is readily available from nonsubstituted cyclohexanone, was selectively converted to cyclohexyne using magnesium bis(2,2,6,6-tetramethylpiperidide) as base. The generated cyclohexyne was trapped by 1,3-diphenylisobenzofuran to afford the cycloadduct. This method was also applied to a benzo-fused cyclohexenyl triflate prepared from α-tetralone. A cyclohexenyl triflate bearing two Me substituents at the 3-position was selectively transformed into the corresponding 1,2-cyclohexadiene. This 1,2-cyclohexadiene reacted with 1,3-diphenylisobenzofuran, styrene, and nitrone to provide the corresponding cycloadducts in good yields. After reading the article, we found that the author used 1,3-Diphenylisobenzofuran(cas: 5471-63-6Application of 5471-63-6)
1,3-Diphenylisobenzofuran(cas: 5471-63-6) is a fluorescent dye. 1,3-Diphenylisobenzofuran is the model compound in studies of singlet fission.Application of 5471-63-6
Referemce:
Benzofuran – Wikipedia,
Benzofuran | C8H6O – PubChem