An article Ruthenium catalyzed alpha-methylation of sulfones with methanol as a sustainable C1 source WOS:000605450500016 published article about 1,4-CONJUGATE ADDITION; ASYMMETRIC-SYNTHESIS; GRIGNARD-REAGENTS; KETONES; ALKYLATION; ALCOHOLS; DERIVATIVES; OLEFINATION; INHIBITORS; NITRILES in [Song, Dingguo; Chen, Linlin; Li, Yujin; Liu, Tao; Yi, Xiao; Liu, Lei; Ling, Fei; Zhong, Weihui] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Peoples R China in 2021, Cited 57. The Name is Isobenzofuran-1(3H)-one. Through research, I have a further understanding and discovery of 87-41-2. Category: benzofurans
Methylation of sulfones, which have an alpha-CH bond, can be easily achieved via a one-step, Ru(II) catalyzed redox neutral reaction using methanol as a sustainable C1 building block. The reaction requires a stoichiometric amount of base and generates only water as a byproduct. A series of value-added methylated sulfones with various functional groups are produced under the reaction conditions from readily available substrates. Mechanism studies shows that a sulfone carbanion addition to an in situ generated aldehyde formed via catalytic dehydrogenation and subsequent catalyst mediated reduction of the alkene by hydrogen may be involved.
Welcome to talk about 87-41-2, If you have any questions, you can contact Song, DG; Chen, LL; Li, YJ; Liu, T; Yi, X; Liu, L; Ling, F; Zhong, WH or send Email.. Category: benzofurans
Reference:
Benzofuran – Wikipedia,
,Benzofuran | C8H6O – PubChem